{"id":"W2094969017","doi":"10.1016/j.sab.2011.12.001","title":"Calibration of double focusing Glow Discharge Mass Spectrometry instruments with pin-shaped synthetic standards","year":2011,"lang":"en","type":"article","venue":"Spectrochimica Acta Part B Atomic Spectroscopy","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":false,"ca_institutions":"National Research Council Canada","funders":"","keywords":"Calibration; Certified reference materials; Analytical Chemistry (journal); Zinc; Mass spectrometry; Copper; Traceability; Analyte; Materials science; Chemistry; Detection limit; Metallurgy; Chromatography; Computer science; Mathematics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003234987,0.0007468135,0.000935282,0.0004139137,0.0003186887,0.0001210612,0.0008980149,0.0002815565,0.02002385],"category_scores_gemma":[0.0000345507,0.0006758536,0.0002867874,0.0009495898,0.0003481201,0.0004551956,0.0001561904,0.0006924053,0.0000218677],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008755805,"about_ca_system_score_gemma":0.000404807,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001375728,"about_ca_topic_score_gemma":0.00004964573,"domain_scores_codex":[0.9956053,0.00004214825,0.0009997271,0.001151986,0.001032223,0.001168574],"domain_scores_gemma":[0.997193,0.00005983416,0.0007786398,0.001489445,0.0001494672,0.0003296346],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001028941,0.0004497671,0.005446182,0.0001356087,0.0002231749,0.000006658609,0.0001731827,2.518367e-7,0.9443576,0.04779802,0.0003448555,0.00003574408],"study_design_scores_gemma":[0.00166192,0.0003671268,0.0002702201,0.000232543,0.0001951437,0.00006299521,0.0001762001,0.0004406007,0.9850783,0.009712468,0.001059487,0.0007430204],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8578158,0.00008289278,0.01846343,0.0004191388,0.000121732,0.0006850876,0.0003862612,0.000722212,0.1213034],"genre_scores_gemma":[0.9511673,0.0002158656,0.04746604,0.00004162564,0.0002898827,0.0001655252,0.0001038336,0.0001604265,0.0003894751],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.120914,"threshold_uncertainty_score":0.9995692,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01616413635372891,"score_gpt":0.2552282661703558,"score_spread":0.2390641298166269,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}