{"id":"W2095002979","doi":"10.1021/ja012006+","title":"Gold(I) Macrocycles and Topologically Chiral [2]Catenanes","year":2002,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":142,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Catenane; Diphosphines; Chemistry; Ferrocene; Ring (chemistry); Stereochemistry; Crystallography; Catalysis; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006487071,0.0001002988,0.0002109996,0.000005687958,0.00006042581,0.00002735986,0.0002108947,0.00005497434,0.0002103491],"category_scores_gemma":[0.00007060888,0.00005793705,0.0003455757,0.00009884535,0.0003590009,0.0000373537,0.0000789315,0.0003315776,0.000002386924],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004253701,"about_ca_system_score_gemma":0.000004728845,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000009257746,"about_ca_topic_score_gemma":1.318374e-7,"domain_scores_codex":[0.9992881,0.00001623988,0.0002317494,0.0001048211,0.0002021962,0.0001568909],"domain_scores_gemma":[0.999325,0.00004332139,0.0003786806,0.0001255041,0.00004518109,0.00008225226],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001680195,0.00004278741,0.0008217233,0.000009866744,0.00004678465,0.00000336058,0.0001118961,0.000002881633,0.9800972,0.000007890915,0.006067094,0.01277175],"study_design_scores_gemma":[0.0005461454,0.00007503634,0.001383632,0.00003834173,0.00007385711,0.0006942454,0.000572408,0.000900656,0.9758368,0.0005413686,0.01912375,0.0002137783],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.996182,0.0003060346,0.00002081888,0.002129441,0.00004241234,0.00001279067,0.000001606287,0.0000120712,0.001292815],"genre_scores_gemma":[0.9965604,0.0004748564,0.00109777,0.0007581806,0.0002495767,5.754782e-7,1.441333e-7,0.000009181055,0.0008493008],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01305666,"threshold_uncertainty_score":0.2362604,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01000090649242012,"score_gpt":0.2163749799590687,"score_spread":0.2063740734666486,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}