{"id":"W2095035867","doi":"10.1080/10934520902958625","title":"Linear free energy relationship based estimates for the congener specific relative reductive defluorination rates of perfluorinated alkyl compounds","year":2009,"lang":"en","type":"article","venue":"Journal of Environmental Science and Health Part A","topic":"Per- and polyfluoroalkyl substances research","field":"Environmental Science","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Okanagan College; University of Winnipeg","funders":"","keywords":"Congener; Chemistry; Alkyl; Reductive dechlorination; Aqueous solution; Branching (polymer chemistry); Stereochemistry; Computational chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001773444,0.0009694415,0.0003944855,0.001536396,0.0002766394,0.0005752983,0.001555745,0.0007213792,0.003455356],"category_scores_gemma":[0.006108591,0.0004864195,0.001303458,0.001069779,0.0003381464,0.00130665,0.0006556017,0.0009272392,0.001082163],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001005924,"about_ca_system_score_gemma":0.0005951616,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004007369,"about_ca_topic_score_gemma":0.003699359,"domain_scores_codex":[0.9993935,0.000162577,0.00003205116,0.0001395424,0.0002298132,0.000042531],"domain_scores_gemma":[0.9974124,0.001761982,0.0003013886,0.0001846059,0.0003189266,0.00002070909],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001357054,0.0001317975,0.0155443,0.000319314,0.0002210061,0.00008818111,0.00009452579,0.9057869,0.01824929,0.007296893,0.001106998,0.05102508],"study_design_scores_gemma":[0.00001575128,0.0001602838,0.006742838,0.00003574301,0.00006537813,0.00008463788,0.00004333682,0.9618447,0.02436933,0.003747023,0.002838669,0.00005231568],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.3586108,0.00171569,0.6212374,0.0001623475,0.00003973504,0.0002396304,0.003791583,0.001810381,0.01239235],"genre_scores_gemma":[0.8740327,0.0008891158,0.1137041,0.000120957,0.00001668816,0.0005229308,0.003659803,0.0005252589,0.006528489],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.004007369,"threshold_uncertainty_score":0.01155925,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.07339726320131235,"score_gpt":0.3517487307588757,"score_spread":0.2783514675575633,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}