{"id":"W2095437454","doi":"10.1002/cbic.200700204","title":"Stereochemical Integrity of Oxazolone Ring‐Containing Jadomycins","year":2007,"lang":"en","type":"article","venue":"ChemBioChem","topic":"Microbial Natural Products and Biosynthesis","field":"Medicine","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Canadian Institutes of Health Research; Dalhousie University","keywords":"Oxazolone; Chemistry; Stereochemistry; Amino acid; Isomerization; Biosynthesis; Enantiomer; Aldehyde; Biochemistry; Catalysis; Enzyme","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000450551,0.0001473546,0.0003472627,0.0000713333,0.00002849107,0.000005860911,0.000108553,0.0001923512,0.0001898016],"category_scores_gemma":[0.0004446328,0.0001157601,0.0001231862,0.000198752,0.0001199375,0.00003434137,0.00007320273,0.000380974,0.00001784205],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006246782,"about_ca_system_score_gemma":0.00004646196,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003191483,"about_ca_topic_score_gemma":0.000003918176,"domain_scores_codex":[0.9989392,0.000006775738,0.0003322471,0.0002775642,0.0001625816,0.0002816488],"domain_scores_gemma":[0.9992319,0.00006744089,0.0001038675,0.0003060692,0.0001574701,0.0001332131],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003944928,0.0001394858,0.001889293,0.0001427392,0.00004576564,0.00001590683,0.0001362267,5.435037e-9,0.9901714,0.0001800102,0.0007468914,0.006137728],"study_design_scores_gemma":[0.0006810862,0.0001224633,0.003503637,0.0001514106,0.00005653124,0.00006089109,0.00017136,0.000002985894,0.9926296,0.00003422448,0.002460892,0.0001249159],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9881692,0.0004323801,0.00004467388,0.0007999259,0.0001003629,0.0001559143,0.000004585854,0.00004910299,0.01024387],"genre_scores_gemma":[0.996439,0.00001723603,0.002349784,0.0002754043,0.0003136759,2.587603e-7,0.00001890442,0.00001535394,0.0005703622],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009673506,"threshold_uncertainty_score":0.472056,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0248688465482951,"score_gpt":0.2825745723963137,"score_spread":0.2577057258480187,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}