{"id":"W2095499154","doi":"10.1016/j.jasms.2006.09.026","title":"Establishment of mass spectrometric fingerprints of novel synthetic cholesteryl neoglycolipids: The presence of a unique <i>C</i>-glycoside species during electrospray ionization and during collision-induced dissociation tandem mass spectrometry","year":2006,"lang":"en","type":"article","venue":"Journal of the American Society for Mass Spectrometry","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Fisheries and Oceans Canada; Memorial University of Newfoundland","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Tandem mass spectrometry; Oxonium ion; Electrospray ionization; Glycosidic bond; Electrospray; Mass spectrometry; Amino sugar; Fragmentation (computing); Disaccharide; Chromatography; Stereochemistry; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000276975,0.000527711,0.0001938165,0.000426318,0.0001809322,0.000229307,0.0002419261,0.0005700769,0.0005518189],"category_scores_gemma":[0.0006047316,0.0001325621,0.0002000163,0.0002306721,0.0003895726,0.0003895825,0.0003352888,0.0004958393,0.0001839176],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002027001,"about_ca_system_score_gemma":0.0002232171,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002832402,"about_ca_topic_score_gemma":0.0003269899,"domain_scores_codex":[0.9997858,0.00002910821,0.00001542853,0.00005547594,0.00008418309,0.00003008424],"domain_scores_gemma":[0.9995968,0.00009728104,0.0001320157,0.00002390011,0.00009379028,0.00005630168],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005528996,0.000005580872,0.0004221365,0.00002322341,0.000004323485,0.00004767265,0.00001466092,0.00002039557,0.9983584,0.00002512824,0.000006496382,0.001016584],"study_design_scores_gemma":[0.00000605561,0.0001348074,0.003930961,0.000005678729,0.00001406266,0.0004607898,0.00003551004,0.0005896374,0.9942887,0.00004702755,0.0004788176,0.000007925023],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9824091,0.001478155,0.01464941,0.00009608382,0.00003158043,0.0000597157,0.0003315567,0.00006703179,0.0008774087],"genre_scores_gemma":[0.9771004,0.0008392996,0.02058284,0.0001535288,0.00001874353,0.00007648216,0.000382827,0.0000340509,0.0008117857],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005700769,"threshold_uncertainty_score":0.001846015,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008136081297358263,"score_gpt":0.236588552906912,"score_spread":0.2284524716095537,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}