{"id":"W2095538853","doi":"10.1021/ic7022538","title":"Structure of the Hydrated Platinum(II) Ion and the <i>cis</i>-Diammineplatinum(II) Complex in Acidic Aqueous Solution: An EXAFS Study","year":2008,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Extended X-ray absorption fine structure; Platinum; Aqueous solution; Ligand (biochemistry); Molecule; Coordination number; Crystallography; Physical chemistry; Inorganic chemistry; Absorption spectroscopy; Ion; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002214355,0.0002364961,0.0004988837,0.00002261763,0.0004104355,0.0000123722,0.0002756737,0.0001234453,0.0005105362],"category_scores_gemma":[0.0002147669,0.0001295174,0.00007073222,0.0003028633,0.0005956306,0.0000605856,0.0002704791,0.000388171,0.000001237625],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004759867,"about_ca_system_score_gemma":0.0001157869,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003265239,"about_ca_topic_score_gemma":0.0001539968,"domain_scores_codex":[0.9984561,0.0001367068,0.0004952388,0.0003153474,0.0003714958,0.0002250867],"domain_scores_gemma":[0.9988852,0.0000940001,0.0001977495,0.0006668401,0.00008350603,0.00007271523],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003961144,0.0002229462,0.009885797,0.00007422402,0.00005001259,0.00001040533,0.004315526,0.000004330609,0.984477,0.000006178483,0.000243241,0.0003141566],"study_design_scores_gemma":[0.005110702,0.0003424575,0.05912152,0.0001063364,0.0001380161,0.0008278541,0.002019427,0.0006727641,0.9307503,0.0001548327,0.0004971454,0.0002586252],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972367,0.0007481496,0.000001884486,0.0005271159,0.00005630383,0.0005263494,0.00001803836,0.0000333344,0.0008520802],"genre_scores_gemma":[0.9989839,0.00002676947,0.00005116644,0.0001642517,0.0001468992,0.000008546652,0.00002107776,0.00002495244,0.0005724246],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05372675,"threshold_uncertainty_score":0.5590013,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03033943465280082,"score_gpt":0.2348531759101483,"score_spread":0.2045137412573475,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}