{"id":"W2095659927","doi":"10.1016/j.poly.2011.05.026","title":"Ruthenium(II) complexes with tetradentate pyridylthioazoimine [N,S,N,N] ligands: Synthesis, crystal structure and spectroscopy","year":2011,"lang":"en","type":"article","venue":"Polyhedron","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":15,"is_retracted":false,"has_abstract":false,"ca_institutions":"Carleton University","funders":"Hashemite University","keywords":"Chemistry; Ruthenium; Crystallography; Acetonitrile; Ligand (biochemistry); Pyridine; Crystal structure; Octahedron; Coordination sphere; Cyclic voltammetry; Stereochemistry; Nuclear magnetic resonance spectroscopy; Thio-; Electrochemistry; Medicinal chemistry; Catalysis; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000119907,0.0003460073,0.0005725586,0.0001387593,0.0002365333,0.00004277569,0.0001427099,0.00009127647,0.001222462],"category_scores_gemma":[0.00005324735,0.0002214301,0.00007996375,0.0001328423,0.000294724,0.000142025,0.00008886503,0.0002418932,0.00001637034],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003166987,"about_ca_system_score_gemma":0.00004842378,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002735806,"about_ca_topic_score_gemma":0.00007237143,"domain_scores_codex":[0.9984568,0.00004038014,0.0003081153,0.0004300985,0.000331631,0.0004330106],"domain_scores_gemma":[0.9991291,0.00006526103,0.0001161707,0.0004100878,0.00004543815,0.0002339517],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001547366,0.0001661887,0.02058543,0.0002356488,0.0002106645,0.00004299628,0.002407822,1.768979e-7,0.9723471,0.0009152871,0.0004337792,0.001107543],"study_design_scores_gemma":[0.0007368188,0.001265175,0.06150967,0.0002314903,0.0002982309,0.0005535707,0.0003003812,0.00003926085,0.9323846,0.0005412051,0.001799704,0.0003399658],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910345,0.001888835,0.00006773863,0.0005390347,0.00009335747,0.0003437714,0.00004953498,0.0001211766,0.005862059],"genre_scores_gemma":[0.992687,0.000138535,0.005826407,0.0002898968,0.0001768694,0.00001842087,0.00001248618,0.00006095793,0.0007894143],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04092424,"threshold_uncertainty_score":0.9996905,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03719920445764252,"score_gpt":0.2395732872469417,"score_spread":0.2023740827892992,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}