{"id":"W2095898421","doi":"10.1039/c0pp00351d","title":"Photodecaging from 9-substituted 2,7-dihydroxy and dimethoxyfluorenes: competition between heterolytic and homolytic pathways","year":2011,"lang":"en","type":"article","venue":"Photochemical & Photobiological Sciences","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":false,"ca_institutions":"Acadia University","funders":"","keywords":"Homolysis; Heterolysis; Chemistry; Carbocation; Methanol; Photochemistry; Medicinal chemistry; Aqueous solution; Solvolysis; Organic chemistry; Radical; Catalysis; Hydrolysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003867224,0.000312948,0.0002813068,0.000221236,0.0003267032,0.0004218225,0.0004863827,0.0006354274,0.004395284],"category_scores_gemma":[0.0003554793,0.0002119638,0.0002424103,0.0001689441,0.0002308789,0.0006880321,0.0002339323,0.0005541888,0.0005451886],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004861789,"about_ca_system_score_gemma":0.0002688468,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001275225,"about_ca_topic_score_gemma":0.00202377,"domain_scores_codex":[0.9998159,0.00002562123,0.000005309639,0.0000323618,0.00002247058,0.00009829885],"domain_scores_gemma":[0.999707,0.0001496427,0.00003771622,0.00003684154,0.0000340281,0.00003474021],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003593043,0.00005280376,0.0003603169,0.0001066185,0.00001230935,0.0002278677,0.0001266307,0.0002511587,0.9914691,0.001248194,0.000118936,0.005666743],"study_design_scores_gemma":[0.000009753724,0.0001249898,0.0006443896,0.000004832479,0.000007075719,0.00008980682,0.00003358131,0.0004037412,0.9979227,0.00009146559,0.0006618467,0.0000058442],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9933651,0.0009201263,0.00207221,0.0000661359,0.00001797554,0.00001383864,0.00009728768,0.00004068318,0.003406549],"genre_scores_gemma":[0.9967759,0.0003827491,0.0005579668,0.00002605475,0.000004759248,0.000007815247,0.0001211337,0.00001387369,0.002109778],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004395284,"threshold_uncertainty_score":0.01470369,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.09332020771604492,"score_gpt":0.2621690102750843,"score_spread":0.1688488025590393,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}