{"id":"W2096021030","doi":"10.1021/ol0619967","title":"Mild and General Conditions for the Cross-Coupling of Aryl Halides with Pentafluorobenzene and Other Perfluoroaromatics","year":2006,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":220,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Aryl; Steric effects; Halide; Yield (engineering); Catalysis; Isopropyl; Medicinal chemistry; Organic chemistry; Combinatorial chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003994535,0.001226964,0.0005879788,0.0005303854,0.0006681774,0.000415555,0.0007257474,0.0007268587,0.003776047],"category_scores_gemma":[0.0005951035,0.0004843428,0.0002499774,0.0003498833,0.0004357205,0.000640255,0.0005673243,0.001406577,0.002122008],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004590076,"about_ca_system_score_gemma":0.0006994332,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001482036,"about_ca_topic_score_gemma":0.003031032,"domain_scores_codex":[0.9994346,0.00008897619,0.00005379597,0.00006885744,0.0002462554,0.0001073199],"domain_scores_gemma":[0.9997464,0.00005201108,0.00007778342,0.00002480192,0.00004723597,0.00005182709],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008452839,0.00004955175,0.0001594799,0.0002347214,0.00001028943,0.0002318466,0.00008187135,0.0003387901,0.9858238,0.0009487844,0.0007764751,0.01125992],"study_design_scores_gemma":[0.00003428952,0.0002118036,0.0009677523,0.00001862904,0.00001924959,0.001345753,0.00005254095,0.0004971266,0.9774746,0.0005060638,0.01884363,0.00002850566],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.4464105,0.01861612,0.5024707,0.000918581,0.0005770402,0.002149182,0.003781575,0.003579205,0.02149709],"genre_scores_gemma":[0.6869283,0.01548191,0.2757352,0.0004211804,0.0002262534,0.001682845,0.005294545,0.0005431358,0.01368662],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.003776047,"threshold_uncertainty_score":0.01263213,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01105771707996952,"score_gpt":0.2531911816482395,"score_spread":0.24213346456827,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}