{"id":"W2096317265","doi":"10.1002/chem.200700199","title":"Cucurbit[8]uril/Cucurbit[7]uril Controlled Off/On Fluorescence of the Acridizinium and 9‐Aminoacridizinium Cations in Aqueous Solution","year":2007,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":76,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Fluorescence; Aqueous solution; Bromide; Dimer; Chemistry; Cucurbituril; Photochemistry; Supramolecular chemistry; Crystallography; Inorganic chemistry; Organic chemistry; Crystal structure; Optics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.001213049,0.0004161081,0.000486867,0.00005472544,0.0003639002,0.0001093151,0.0008262604,0.0001428035,0.0003235162],"category_scores_gemma":[0.0006698511,0.0003444684,0.0003094227,0.000271919,0.0004033303,0.0001127386,0.0002283542,0.001236846,0.00001155322],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001561141,"about_ca_system_score_gemma":0.0001845979,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000804988,"about_ca_topic_score_gemma":0.000003613616,"domain_scores_codex":[0.9971048,0.0001481175,0.001069714,0.0004867037,0.0005486124,0.0006421137],"domain_scores_gemma":[0.9978945,0.000239916,0.0006580442,0.0007265463,0.0001879151,0.0002931289],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005237982,0.0002648935,0.0009422868,0.0001678436,0.00006652255,0.0002675231,0.0003655487,0.00002501247,0.9925234,0.00002948442,0.0008636376,0.00396005],"study_design_scores_gemma":[0.005036855,0.00003842639,0.001375835,0.0005144905,0.00008742547,0.001452646,0.0005907264,0.0008252402,0.9828857,0.0001085799,0.006645017,0.000439086],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9596532,0.001460692,0.0001318524,0.0004834972,0.0001705638,0.0001106291,0.00002662841,0.00004865518,0.03791426],"genre_scores_gemma":[0.9972852,0.0001600755,0.0002585004,0.0001083808,0.0006156543,0.000006145307,0.00001700887,0.00005807005,0.001490953],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03763198,"threshold_uncertainty_score":0.9999008,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01206960797964693,"score_gpt":0.2235197078111251,"score_spread":0.2114500998314782,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}