{"id":"W2096367102","doi":"10.1107/s1600536803011772","title":"[(<i>R,R</i>)-1-(<i>N</i>-Benzylideneamino)-2-(diphenylphosphino)cyclohexane-κ<sup>2</sup><i>N,P</i>]dichloro(triphenylphosphine-κ<i>P</i>)ruthenium(II)","year":2003,"lang":"he","type":"article","venue":"Acta Crystallographica Section E Structure Reports Online","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Triphenylphosphine; Ruthenium; Cyclohexane; Medicinal chemistry; Chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004964395,0.0001725405,0.0001908077,0.0001055833,0.0001144865,0.0002779003,0.0003716178,0.00013619,0.003552391],"category_scores_gemma":[0.0001195211,0.0001156261,0.0000464557,0.0001797232,0.0001625161,0.0001752409,0.0001285895,0.0002265769,0.001064892],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002542999,"about_ca_system_score_gemma":0.000179454,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00125733,"about_ca_topic_score_gemma":0.00170824,"domain_scores_codex":[0.9999417,0.000008543703,0.000002314564,0.00001454917,0.00001322097,0.00001967188],"domain_scores_gemma":[0.999966,0.000006933345,0.00001254733,0.000004188819,0.000004386016,0.000005879524],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004080171,0.00004474715,0.0003186152,0.0004379677,0.00001690716,0.0002202601,0.00004477084,0.0004178033,0.9782733,0.001797717,0.002187609,0.01583228],"study_design_scores_gemma":[0.0001652049,0.0002982623,0.001799991,0.00002143859,0.00001802339,0.0007168799,0.00007257416,0.0007752285,0.9637503,0.0002161187,0.03215028,0.00001565196],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.917797,0.007712107,0.01029823,0.0004042287,0.000206433,0.00009465842,0.001340238,0.001223009,0.06092409],"genre_scores_gemma":[0.9854351,0.001997516,0.002327751,0.00008309906,0.00002986384,0.00002683188,0.001001517,0.00005769762,0.009040656],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003552391,"threshold_uncertainty_score":0.01188391,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006589603733430694,"score_gpt":0.2216554036672827,"score_spread":0.215065799933852,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}