{"id":"W2097783775","doi":"10.1002/chin.200447020","title":"A New Class of Chiral P,N‐Ligands and Their Application in Palladium‐Catalyzed Asymmetric Allylic Substitution Reaction.","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"","keywords":"Chemistry; Palladium; Allylic rearrangement; Substitution (logic); Catalysis; Substitution reaction; Medicinal chemistry; Stereochemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001430417,0.0001761081,0.0002844959,0.0002713584,0.00003978624,0.00001870725,0.0001726518,0.0001818908,0.00001713584],"category_scores_gemma":[0.0001259859,0.0001537307,0.0000954524,0.001003155,0.00005315226,0.0001948427,0.00004621412,0.0001310555,0.00001188205],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000214594,"about_ca_system_score_gemma":0.0001109175,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004310539,"about_ca_topic_score_gemma":0.0000460944,"domain_scores_codex":[0.998983,2.261099e-7,0.0003990165,0.0002400568,0.000173007,0.0002046918],"domain_scores_gemma":[0.9992231,0.0000636619,0.0002234298,0.0003402557,0.00004330462,0.0001062489],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004634961,0.00008314528,0.00130789,0.0001056871,0.00005398749,7.786467e-7,0.000437652,0.000003950901,0.07607327,0.001344681,0.00006863604,0.920474],"study_design_scores_gemma":[0.001048039,0.000007969755,0.003414514,0.00004216737,0.00003118246,0.00001624438,0.0003374298,0.00004751597,0.9918879,0.0005460978,0.002443029,0.0001778908],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6480284,0.001140632,0.0003593485,0.0001250271,0.00003277039,0.0001415649,0.00001691122,0.00007719669,0.3500782],"genre_scores_gemma":[0.9988222,0.0001906736,0.000100856,0.00001545052,0.00008334721,0.00002787601,0.0001335016,0.00001312894,0.0006129671],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.9202961,"threshold_uncertainty_score":0.6268955,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007999795367246845,"score_gpt":0.2098905781874477,"score_spread":0.2018907828202009,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}