{"id":"W2097841695","doi":"10.1002/1521-3765(20020104)8:1<177::aid-chem177>3.0.co;2-h","title":"On the Mechanism of the Copper-Catalyzed Cyclopropanation Reaction","year":2002,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":98,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Teknologi og Produktion, Det Frie Forskningsråd","keywords":"Cyclopropanation; Mechanism (biology); Copper; Catalysis; Chemistry; Reaction mechanism; Combinatorial chemistry; Organic chemistry; Philosophy; Epistemology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003386976,0.0007305535,0.0005853988,0.0002673607,0.0004653436,0.0007722111,0.001059636,0.0004224445,0.003472741],"category_scores_gemma":[0.0004267797,0.0002920676,0.0002861262,0.0001977902,0.000520061,0.0008205352,0.0002944382,0.0005747842,0.0006550034],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007570985,"about_ca_system_score_gemma":0.0006113266,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001903889,"about_ca_topic_score_gemma":0.001338979,"domain_scores_codex":[0.9999219,0.00001240864,0.000003128105,0.00001545955,0.00002151469,0.00002568805],"domain_scores_gemma":[0.9999093,0.00003598245,0.00002445876,0.000009709467,0.00001338345,0.00000725907],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001220722,0.0003700099,0.005596812,0.003001669,0.0003550362,0.004618857,0.0006985485,0.3375115,0.3108886,0.2491651,0.005164741,0.08140831],"study_design_scores_gemma":[0.0002671737,0.0004900384,0.003340145,0.0001338692,0.0002714208,0.001194327,0.0003079764,0.5650648,0.3650415,0.04917349,0.01453574,0.0001794452],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9347953,0.006006665,0.03706282,0.0009285408,0.0001665861,0.0001801529,0.0004040208,0.0004074059,0.02004849],"genre_scores_gemma":[0.9906781,0.002595365,0.004322754,0.00003654113,0.00001545155,0.00006456443,0.0001197629,0.00001488685,0.002152623],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003472741,"threshold_uncertainty_score":0.01161748,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01977953980226179,"score_gpt":0.1985254242845454,"score_spread":0.1787458844822836,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}