{"id":"W2097841695","doi":"10.1002/1521-3765(20020104)8:1<177::aid-chem177>3.0.co;2-h","title":"On the Mechanism of the Copper-Catalyzed Cyclopropanation Reaction","year":2002,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":98,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Teknologi og Produktion, Det Frie Forskningsråd","keywords":"Cyclopropanation; Mechanism (biology); Copper; Catalysis; Chemistry; Reaction mechanism; Combinatorial chemistry; Organic chemistry; Philosophy; Epistemology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004912421,0.0002350594,0.0001677977,0.00002542287,0.0004599442,0.00008080397,0.0006908853,0.00006790851,0.003033884],"category_scores_gemma":[0.0003745532,0.0001436447,0.0002431305,0.0001776815,0.0000929173,0.0000957675,0.00009979156,0.0009563121,0.0001704665],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002041636,"about_ca_system_score_gemma":0.00003009098,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002027611,"about_ca_topic_score_gemma":2.621994e-7,"domain_scores_codex":[0.9982655,0.0001299871,0.0004822001,0.0002550316,0.0006094882,0.0002578069],"domain_scores_gemma":[0.9982745,0.00009009138,0.0006516287,0.0006960999,0.0001748941,0.0001127801],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001752041,0.00007797471,0.000006474001,0.00004899919,0.00003606895,0.00002261824,0.000303848,0.00001086043,0.9922001,0.0003446871,0.001301038,0.005629828],"study_design_scores_gemma":[0.000661075,0.00001549826,0.00003932049,0.0001751435,0.00005789114,0.0009710282,0.001197517,0.0008381047,0.9879538,0.0004557255,0.007439065,0.0001958725],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8679332,0.00008279886,0.0001279147,0.0008884204,0.0002640959,0.00007569259,0.00001029495,0.00006686138,0.1305507],"genre_scores_gemma":[0.9954401,0.0000983255,0.00006226008,0.0000842451,0.0004455318,0.000004383776,0.000006585902,0.00005963393,0.003798941],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1275069,"threshold_uncertainty_score":0.9978775,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01977953980226179,"score_gpt":0.1985254242845454,"score_spread":0.1787458844822836,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}