{"id":"W2097881517","doi":"10.1139/v02-145","title":"Synthesis and reactivity of palladium and platinum diimine complexes containing boronate esters","year":2002,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Diimine; Platinum; Palladium; Medicinal chemistry; Cisplatin; Stereochemistry; DNA; Reactivity (psychology); Organic chemistry; Biochemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002174928,0.0003435058,0.0002555774,0.0002230184,0.0001464404,0.0003080055,0.0003976507,0.0002946628,0.001189545],"category_scores_gemma":[0.0003294252,0.0003036498,0.0001364611,0.0001733579,0.0002233772,0.0002603388,0.0002042337,0.00025835,0.0003771855],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005309817,"about_ca_system_score_gemma":0.0001551878,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007441526,"about_ca_topic_score_gemma":0.001151979,"domain_scores_codex":[0.9998343,0.0000273756,0.00001687482,0.00003520519,0.00005256971,0.00003363518],"domain_scores_gemma":[0.9999012,0.00002174635,0.00002333495,0.000009109312,0.00001384533,0.00003074487],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001710046,0.00001530257,0.0001160996,0.00007980662,0.000009255775,0.00006403115,0.00002646659,0.0002697942,0.9969496,0.0002374952,0.00004541329,0.002015673],"study_design_scores_gemma":[0.00002451342,0.000122735,0.0003214458,0.000003763731,0.000008007408,0.0001223587,0.000008991301,0.0003495423,0.9977302,0.0000327161,0.001270889,0.000004949492],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9855376,0.002706442,0.00580143,0.0001036533,0.00002987401,0.00006776452,0.0001998453,0.00008959208,0.005463905],"genre_scores_gemma":[0.9889509,0.001082991,0.005070613,0.00003746588,0.000004630654,0.00002929232,0.0003182881,0.00002406939,0.004481736],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001189545,"threshold_uncertainty_score":0.003979445,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01758280118296151,"score_gpt":0.1939900399187682,"score_spread":0.1764072387358067,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}