{"id":"W2098576244","doi":"10.1139/v00-057","title":"Enantiomerically pure decalinic structures from carbohydrates using intramolecular Diels-Alder and Ferrier carbocyclization","year":2000,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Intramolecular force; Cycloaddition; Diene; Double bond; Diels–Alder reaction; Enone; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002461357,0.0005587675,0.0002438275,0.0003233378,0.0002234963,0.0004072855,0.0002495212,0.0002035048,0.001528419],"category_scores_gemma":[0.0001812084,0.0001429868,0.000246692,0.000257294,0.0002738992,0.0004503018,0.0003834826,0.0006401934,0.000591712],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003873912,"about_ca_system_score_gemma":0.0002921718,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004837857,"about_ca_topic_score_gemma":0.001380851,"domain_scores_codex":[0.9998299,0.00001920821,0.0000121812,0.00003616494,0.00004214568,0.00006031674],"domain_scores_gemma":[0.9999455,0.000007465608,0.00001445173,0.00001299997,0.000008656755,0.00001085247],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001808878,0.000120599,0.0002816048,0.000289008,0.0000264792,0.0006278826,0.0002726343,0.001331941,0.9388016,0.01122821,0.0006174365,0.04622176],"study_design_scores_gemma":[0.00002257874,0.0002581524,0.0004696467,0.00001140203,0.00001826864,0.0005075734,0.00003501668,0.0003780994,0.9724801,0.0006984379,0.0251003,0.00002039196],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8521076,0.008311747,0.08196371,0.0006328277,0.0003439106,0.000520076,0.0007708615,0.0006505384,0.05469861],"genre_scores_gemma":[0.9510512,0.004551306,0.03262567,0.0001121215,0.000045275,0.0001033044,0.0004784486,0.0001220205,0.0109107],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001528419,"threshold_uncertainty_score":0.005113065,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009291525441325417,"score_gpt":0.2088133143349148,"score_spread":0.1995217888935894,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}