{"id":"W2099001497","doi":"10.1039/b704211f","title":"Total synthesis of (−)-conocarpan and assignment of the absolute configuration by chemical methods","year":2007,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Traditional and Medicinal Uses of Annonaceae","field":"Biochemistry, Genetics and Molecular Biology","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Absolute configuration; Chemistry; Total synthesis; Degradation (telecommunications); Stereochemistry; Combinatorial chemistry; Computational chemistry; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002353429,0.00006604764,0.0001079039,0.00001024046,0.00003669251,0.000002393519,0.0002914522,0.00008394298,0.00000486653],"category_scores_gemma":[0.000214464,0.00005141622,0.00006140606,0.00005006146,0.0004511216,0.000002681113,0.0001588098,0.00008575875,3.140756e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000009814709,"about_ca_system_score_gemma":0.00002759881,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000134031,"about_ca_topic_score_gemma":0.000001171138,"domain_scores_codex":[0.9994631,0.00004292442,0.0002248101,0.000102183,0.00008292445,0.00008402362],"domain_scores_gemma":[0.9991053,0.0001914361,0.0001025862,0.000483839,0.0000655726,0.00005123179],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002211305,0.00007748737,0.0001039486,0.00001146233,0.00002882759,1.770735e-8,0.0000244215,2.205012e-7,0.9929411,0.001047199,0.0006418448,0.005101317],"study_design_scores_gemma":[0.0001274451,0.00002372214,0.001817127,0.00002077144,0.00003005739,0.000006630165,0.00006954874,0.00001191221,0.99257,0.000172624,0.005096056,0.00005411381],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9892195,0.001453417,0.003196989,0.001433566,0.00002820811,0.0001263283,0.00006101694,0.00000486434,0.004476123],"genre_scores_gemma":[0.9922791,0.0001334746,0.007325333,0.00008762642,0.00002335883,0.00001102343,0.00007814246,0.000005485552,0.0000564953],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005047203,"threshold_uncertainty_score":0.2096693,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01824952110089582,"score_gpt":0.3098422639048562,"score_spread":0.2915927428039604,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}