{"id":"W2099406727","doi":"10.1351/pac-con-09-08-08","title":"Proximity-assisted cycloaddition reactions of ω-azido cyanohydrin ethers: Synthesis of diversely functionalized bicyclic tetrazoles","year":2010,"lang":"en","type":"article","venue":"Pure and Applied Chemistry","topic":"Synthesis of Tetrazole Derivatives","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Université de Montréal; Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Chemistry; Bicyclic molecule; Cyanohydrin; Cycloaddition; Trimethylsilyl cyanide; Trimethylsilyl; Nitrile; Cyanide; Aryl; Organic chemistry; Combinatorial chemistry; Medicinal chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001356441,0.0002792617,0.0004339058,0.00006154676,0.0001181721,0.00002307276,0.0002545541,0.0003684026,0.003351385],"category_scores_gemma":[0.0002959625,0.0002803566,0.0001510448,0.0001805848,0.0004224922,0.0001157771,0.00007815643,0.0004035576,0.000007068049],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002430546,"about_ca_system_score_gemma":0.00005264706,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001907417,"about_ca_topic_score_gemma":0.000003921399,"domain_scores_codex":[0.9984854,0.000008934092,0.0005022326,0.0004162058,0.0003486154,0.0002385629],"domain_scores_gemma":[0.9983406,0.0004985263,0.0004713578,0.0004765668,0.00009525923,0.0001176604],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001115053,0.0002938326,0.0008965603,0.0007531528,0.0001823504,0.000001249218,0.00007744976,0.000003943889,0.9846731,0.0002281684,0.0001908596,0.01258779],"study_design_scores_gemma":[0.0004712828,0.000003530698,0.003202091,0.0001120007,0.0001320297,0.00001939146,0.0007019628,0.00001556471,0.9902894,0.0005536192,0.00423569,0.0002634758],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9271715,0.00006203499,0.00001578156,0.0001173929,0.00003800368,0.00008293744,0.000215839,0.0001020867,0.07219437],"genre_scores_gemma":[0.9984186,0.000059367,0.0008310452,0.00001115302,0.0001508248,0.0001244505,0.00008097031,0.00003540615,0.0002881571],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07190621,"threshold_uncertainty_score":0.9999648,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0110337240753651,"score_gpt":0.2176956940118793,"score_spread":0.2066619699365142,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}