{"id":"W2099421650","doi":"10.1039/c3dt51212f","title":"A detailed kinetic analysis of rhodium-catalyzed alkyne hydrogenation","year":2013,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; British Columbia Knowledge Development Fund; University of Victoria","keywords":"Rhodium; Alkyne; Alkene; Catalysis; Dissociation (chemistry); Chemistry; Triphenylphosphine; Alkane; Mass spectrometry; Reaction mechanism; Photochemistry; Reaction rate; Medicinal chemistry; Physical chemistry; Organic chemistry; Chromatography","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001010127,0.0001713288,0.0003765403,0.0008491255,0.0001112386,0.00003115235,0.0002115708,0.0001311322,0.01898789],"category_scores_gemma":[0.00003328082,0.0001712021,0.0004752332,0.003089752,0.00006449951,0.0001629126,0.000005541157,0.0001380639,0.0001860563],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007332805,"about_ca_system_score_gemma":0.00003725592,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004484991,"about_ca_topic_score_gemma":0.0002831764,"domain_scores_codex":[0.9985572,0.00002536048,0.0005189325,0.0003063628,0.0003704281,0.0002216815],"domain_scores_gemma":[0.9988819,0.000106774,0.0001960428,0.0004703311,0.0002019309,0.0001430073],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004126652,0.001286983,0.00495931,0.0001844194,0.01054866,0.000004190803,0.001434108,0.01689417,0.8439454,0.0004281549,0.0001741075,0.1200992],"study_design_scores_gemma":[0.001378622,0.00001882226,0.007243244,0.00001461122,0.007206038,0.000006272594,0.0007093973,0.1711933,0.8085998,0.0001215571,0.002979854,0.0005285187],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8793176,0.0001729201,0.1062477,0.0002756388,0.00005241734,0.0001532871,0.0001721186,0.0001658566,0.01344241],"genre_scores_gemma":[0.99709,0.00005285682,0.0004077602,0.00003476597,0.0000174726,0.0001194924,0.0005615347,0.00001985682,0.001696199],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1542991,"threshold_uncertainty_score":0.9819089,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01027105998488019,"score_gpt":0.2315442081383777,"score_spread":0.2212731481534976,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}