{"id":"W2100065383","doi":"10.1002/anie.201507635","title":"Syntheses and Structures of F<sub>6</sub>XeNCCH<sub>3</sub> and F<sub>6</sub>Xe(NCCH<sub>3</sub>)<sub>2</sub>","year":2015,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Moiety; Raman spectroscopy; Acetonitrile; Crystallography; Chemistry; Molecule; Octahedron; Molecular geometry; Octahedral molecular geometry; Phase (matter); Crystal structure; Stereochemistry; Physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.0007389342,0.001404668,0.001262872,0.0005745184,0.0005276653,0.0004895065,0.00101172,0.001464687,0.00008419883],"category_scores_gemma":[0.001040526,0.00142032,0.0005339366,0.0006050917,0.0009017347,0.001310573,0.0006998426,0.001615382,0.000109917],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008654505,"about_ca_system_score_gemma":0.0004806356,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008040119,"about_ca_topic_score_gemma":0.0001266442,"domain_scores_codex":[0.9928179,0.0001201353,0.001782945,0.001822956,0.002166905,0.001289127],"domain_scores_gemma":[0.9946889,0.0007572327,0.001274288,0.001003319,0.001453899,0.0008223957],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005714924,0.0003669272,0.0004510882,0.0004563241,0.0008814289,0.0001510559,0.0007239365,0.0000894452,0.9681597,0.0007464823,0.01702381,0.01037833],"study_design_scores_gemma":[0.002714129,0.0002195003,0.0008180859,0.001008996,0.0004853148,0.0006713838,0.0006048225,0.0004877442,0.9827774,0.006926318,0.001783031,0.001503324],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9874814,0.002069512,0.0003365723,0.000883745,0.003283205,0.0004614908,0.0009887093,0.0004025035,0.004092831],"genre_scores_gemma":[0.9880918,0.004502337,0.00009978674,0.0004062219,0.004676839,0.0001462753,0.001761572,0.0002670209,0.0000481235],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01524078,"threshold_uncertainty_score":0.9998704,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01332760775391367,"score_gpt":0.2222383574415188,"score_spread":0.2089107496876051,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}