{"id":"W2100321786","doi":"10.18433/j3330x","title":"Medicinal use of Sceletium: Characterization of Phytochemical Components of Sceletium Plant Species using HPLC with UV and Electrospray Ionization – Tandem Mass Spectroscopy","year":2015,"lang":"en","type":"article","venue":"Journal of Pharmacy & Pharmaceutical Sciences","topic":"Chemical synthesis and alkaloids","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Rhodes University","keywords":"Chemistry; Electrospray ionization; Phytochemical; Tandem mass spectrometry; Electrospray; Chromatography; Mass spectrometry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001933014,0.0004305294,0.0003278261,0.00126539,0.0004153849,0.0002884796,0.0001964451,0.0004573948,0.001602737],"category_scores_gemma":[0.0004278902,0.0001221875,0.0003643988,0.000613871,0.0003242095,0.0004016112,0.0002464435,0.0004692479,0.0003100011],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001522152,"about_ca_system_score_gemma":0.0002856604,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006147478,"about_ca_topic_score_gemma":0.00163584,"domain_scores_codex":[0.999861,0.00001839733,0.00001436595,0.00003537909,0.00005938919,0.00001145689],"domain_scores_gemma":[0.9997017,0.00006767596,0.00008441621,0.00002396704,0.00008584146,0.00003650253],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002867987,0.0000968601,0.004055324,0.0006736199,0.00005236919,0.0003916685,0.0001309214,0.00009290929,0.9780664,0.00006326909,0.00006714725,0.01602264],"study_design_scores_gemma":[0.00009281044,0.002599008,0.1518236,0.000345939,0.0004356724,0.005805703,0.000373417,0.001266822,0.8245261,0.0002841847,0.01236437,0.00008250198],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9759703,0.01316703,0.004377859,0.0001838242,0.00003723526,0.0001499942,0.0009359319,0.000113729,0.005064155],"genre_scores_gemma":[0.9844068,0.004480441,0.007731964,0.0002205359,0.00004686594,0.00006553398,0.0007951478,0.00002320148,0.002229506],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001602737,"threshold_uncertainty_score":0.005361676,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1108222838155436,"score_gpt":0.3341589299691603,"score_spread":0.2233366461536167,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}