{"id":"W2100698743","doi":"10.1039/b710708k","title":"Optically sensed, molecular shuttles driven by acid–base chemistry","year":2007,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":68,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Rotaxane; Pyridinium; Chemistry; Bistability; Base (topology); Fluorescence; Molecular recognition; Acid–base reaction; Photochemistry; Molecule; Supramolecular chemistry; Organic chemistry; Materials science; Optics; Optoelectronics; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003341725,0.0005184173,0.0003409001,0.0001537555,0.0001204286,0.0004692169,0.0004538709,0.0004412218,0.001472795],"category_scores_gemma":[0.0003871329,0.000214704,0.0001584361,0.0001178562,0.0003591675,0.0005372114,0.0003215141,0.0006233464,0.000300149],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002439852,"about_ca_system_score_gemma":0.0001286453,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001026321,"about_ca_topic_score_gemma":0.0001649912,"domain_scores_codex":[0.9997935,0.00003054057,0.00001443939,0.00006851259,0.00003958536,0.00005356123],"domain_scores_gemma":[0.9997256,0.00004354667,0.0001181165,0.00002538604,0.00002624827,0.000061045],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001015221,0.00001058247,0.00005588647,0.00003576154,0.000003974073,0.00003494572,0.00002119618,0.00008613038,0.9981844,0.0003161037,0.00003336965,0.001116171],"study_design_scores_gemma":[0.00002237509,0.000120576,0.0001433126,0.000001528478,0.000004881475,0.00005382151,0.000004995249,0.0003136309,0.9984843,0.00003123535,0.0008137065,0.000005656393],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9879552,0.00066483,0.009797681,0.0000923785,0.00006756017,0.00005536505,0.0001205169,0.0002561534,0.0009903271],"genre_scores_gemma":[0.9916066,0.000249836,0.006466292,0.00005420429,0.00001728119,0.00005779511,0.0001191893,0.00003348892,0.001395373],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001472795,"threshold_uncertainty_score":0.004927039,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01145227523454002,"score_gpt":0.2506697359447911,"score_spread":0.2392174607102511,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}