{"id":"W2101032057","doi":"10.1002/hlca.200390234","title":"1,3‐Oxathiolanes from the Reaction of Aromatic and Enolized Thioketones with Monosubstituted Oxiranes","year":2003,"lang":"en","type":"article","venue":"Helvetica Chimica Acta","topic":"Organic Chemistry Cycloaddition Reactions","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institute of Particle Physics","funders":"","keywords":"Chemistry; Adduct; Lewis acids and bases; Medicinal chemistry; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000206223,0.0006659235,0.000145712,0.0001660295,0.0001057073,0.000191811,0.0002187529,0.0002631046,0.001993249],"category_scores_gemma":[0.0001678092,0.0001647681,0.0002210542,0.0001615849,0.0001939326,0.0002733633,0.0002345355,0.0004301064,0.0006519085],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001931782,"about_ca_system_score_gemma":0.0002395062,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003304305,"about_ca_topic_score_gemma":0.0009982137,"domain_scores_codex":[0.9998572,0.00002941332,0.000009178882,0.00002065901,0.00002984243,0.0000537382],"domain_scores_gemma":[0.9998564,0.00001950891,0.00003837886,0.00001875638,0.00002220109,0.00004484933],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001459744,0.00001924933,0.0001251949,0.0000861451,0.0000117131,0.0001525202,0.00007382048,0.0002331476,0.9975841,0.0001560933,0.00003978398,0.001372364],"study_design_scores_gemma":[0.000007538706,0.0002363233,0.0006376292,0.000004627723,0.000007472139,0.000112211,0.00002319982,0.0001114019,0.996831,0.00002945617,0.001993844,0.000005368478],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9905191,0.0009393427,0.003373828,0.00005806142,0.00005360537,0.00004461252,0.0003613654,0.00007579687,0.004574316],"genre_scores_gemma":[0.9917139,0.000704236,0.002087249,0.00002578436,0.000008219678,0.00002192521,0.0004508208,0.00002600134,0.004961828],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001993249,"threshold_uncertainty_score":0.006668031,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009062568140271954,"score_gpt":0.2025732440735136,"score_spread":0.1935106759332416,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}