{"id":"W2101454885","doi":"10.1039/c4cp01105h","title":"The one-electron reduction of dithiolate and diselenolate ligands","year":2014,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Organic and Molecular Conductors Research","field":"Materials Science","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Atlantic Canada Opportunities Agency","keywords":"Reduction (mathematics); Electron; Chemistry; One-electron reduction; Crystallography; Physics; Physical chemistry; Nuclear physics; Electrochemistry; Mathematics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001367836,0.0001395659,0.0002088381,0.000003000589,0.0001104865,0.00004573893,0.0002476461,0.00005791564,0.000008149686],"category_scores_gemma":[0.0001059906,0.0001036782,0.00007061238,0.0001150125,0.0003445155,0.00007866099,0.0001512031,0.0002350583,0.00001265833],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002782404,"about_ca_system_score_gemma":0.00003412165,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004996341,"about_ca_topic_score_gemma":3.495403e-8,"domain_scores_codex":[0.998908,0.00002186085,0.0001653782,0.000294972,0.0003033853,0.0003063764],"domain_scores_gemma":[0.9992839,0.0001128645,0.00008648331,0.0003221638,0.00007939478,0.0001152247],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003187581,0.00009472204,0.000003713584,0.0000606395,0.00001033301,9.503451e-8,0.00007553669,0.000002123199,0.9973243,0.0008738386,0.0000465195,0.001476322],"study_design_scores_gemma":[0.0001814369,0.00002918518,0.00001262383,0.00001458321,0.00002122391,0.000001785538,0.00001003141,0.0006170485,0.9851578,0.01366529,0.0001671538,0.0001217821],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9985569,0.00004927935,0.0001793465,0.0001706315,0.00002565313,0.00006026539,0.000004327959,0.00003485185,0.0009187656],"genre_scores_gemma":[0.9992203,0.00002200585,0.0000372825,0.000007557108,0.0005727987,0.000008307262,0.000007651363,0.00001915819,0.0001049432],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01279145,"threshold_uncertainty_score":0.4227876,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01014561955061335,"score_gpt":0.2487191215069044,"score_spread":0.238573501956291,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}