{"id":"W2101669898","doi":"10.1139/v07-131","title":"Synthesis of the bulky <i>m</i>-terphenyl phenol Ar*OH (Ar* = C<sub>6</sub>H<sub>3</sub>-2,6-Mes<sub>2</sub>, Mes = 2,4,6-trimethylphenyl) and the preparation and structural characterization of several of its metal complexes","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":52,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Nitrobenzene; Terphenyl; Electron paramagnetic resonance; Phenol; Yield (engineering); Spectroscopy; Nuclear magnetic resonance spectroscopy; Medicinal chemistry; Single crystal; Crystallography; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006797186,0.0002911562,0.0001679609,0.0001174472,0.0001097756,0.0001353566,0.000314177,0.0002033795,0.002312162],"category_scores_gemma":[0.00009373687,0.0001316844,0.0001261971,0.0001539831,0.0001001918,0.000179972,0.0002004767,0.0003707006,0.001039594],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002008603,"about_ca_system_score_gemma":0.0002032042,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003726228,"about_ca_topic_score_gemma":0.0008541592,"domain_scores_codex":[0.9999473,0.000004511778,0.000003454843,0.00001369293,0.00001775082,0.00001330701],"domain_scores_gemma":[0.99992,0.000007105828,0.00002667899,0.00001291252,0.00001690444,0.00001636786],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000400326,0.000008325099,0.00005414392,0.00006186119,0.000002632521,0.00003619059,0.0000107469,0.00007150767,0.9971641,0.0001110639,0.00006754538,0.002371902],"study_design_scores_gemma":[0.000009199227,0.0001749484,0.0005695216,0.000002130732,0.000006785323,0.0001432226,0.00001083865,0.0002390026,0.9934325,0.00003266897,0.005375268,0.000003850192],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9572225,0.002237777,0.02870313,0.0001620136,0.00005322961,0.0001830362,0.001664541,0.0003850398,0.009388714],"genre_scores_gemma":[0.9599923,0.001565577,0.0271707,0.0001074294,0.00001418865,0.0001055837,0.001500823,0.00009314239,0.009450075],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002312162,"threshold_uncertainty_score":0.007734895,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007590965679376372,"score_gpt":0.184814841999848,"score_spread":0.1772238763204716,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}