{"id":"W2101820203","doi":"10.1002/chin.201420054","title":"ChemInform Abstract: 2‐Pyridonate Titanium Complexes for Chemoselectivity. Accessing Intramolecular Hydroaminoalkylation over Hydroamination.","year":2014,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Hydroamination; Chemoselectivity; Intramolecular force; Titanium; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004062415,0.000385041,0.0004005393,0.0002136312,0.0002895295,0.0002044738,0.0004401658,0.0003188105,0.00206212],"category_scores_gemma":[0.0005057447,0.0004054794,0.0002799509,0.0005488985,0.0001299255,0.0007714416,0.00009783924,0.0002531806,0.00006396401],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003525601,"about_ca_system_score_gemma":0.00007284278,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001793173,"about_ca_topic_score_gemma":0.000005297356,"domain_scores_codex":[0.9978111,1.552829e-7,0.000641001,0.0004486482,0.0005593149,0.0005397194],"domain_scores_gemma":[0.9983753,0.000243396,0.0004652164,0.0004967013,0.0002243388,0.0001950357],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003549761,0.0001002265,0.00008010536,0.0003516865,0.0001074468,8.80054e-7,0.0002591205,0.000007993742,0.07653995,0.00114402,0.005771104,0.915602],"study_design_scores_gemma":[0.001072963,0.00001427709,0.0003819331,0.00003285253,0.00007791664,0.000008743069,0.000091094,0.008779523,0.8674558,0.0004795626,0.1211225,0.0004828278],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.0475513,0.00009522808,0.0006025495,0.000116676,0.00009871522,0.0002169225,0.00003956967,0.0002937132,0.9509853],"genre_scores_gemma":[0.9825687,0.00001275733,0.0002001465,0.0002455973,0.0003331154,0.0001174558,0.00113176,0.00005980334,0.01533062],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.9356547,"threshold_uncertainty_score":0.9998397,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01140436025309177,"score_gpt":0.2494355245511123,"score_spread":0.2380311642980205,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}