{"id":"W2102206131","doi":"10.1021/jo048591p","title":"Development of Electrochemical Processes for Nitrene Generation and Transfer","year":2005,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":67,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Nitrene; Overpotential; Chemoselectivity; Electrochemistry; Combinatorial chemistry; Molecule; Acceptor; Reactive intermediate; Anode; Reagent; Photochemistry; Organic chemistry; Electrode; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001652583,0.00007801789,0.0001369349,0.000007468643,0.00005824323,0.000008812154,0.0001257898,0.00005763303,0.0003150542],"category_scores_gemma":[0.0001123216,0.00005338129,0.0000366248,0.00004734308,0.00003099331,0.00004624703,0.000008648454,0.00009679489,3.75172e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004780299,"about_ca_system_score_gemma":0.0002377209,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":1.406161e-7,"about_ca_topic_score_gemma":0.000002143698,"domain_scores_codex":[0.999398,0.000002061518,0.0003356136,0.00005791122,0.0001166607,0.00008974066],"domain_scores_gemma":[0.9995178,0.0000910519,0.0001204792,0.00008729382,0.0001421244,0.00004126679],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003646213,0.00005880208,0.00001842837,0.0001473644,0.00005844616,7.362843e-8,0.0003877758,8.25996e-7,0.9941494,0.000001042681,0.00008797085,0.005053374],"study_design_scores_gemma":[0.0003158778,0.00000488691,0.00001207944,0.00003515923,0.0000907303,0.0001681479,0.0002328722,0.00001477227,0.995371,0.00001530246,0.003679901,0.0000592742],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957008,0.0008015358,0.002780472,0.0003081041,0.000006951448,0.00001814553,0.00000218786,0.000004293052,0.000377493],"genre_scores_gemma":[0.9974957,0.0001824051,0.001725556,0.00001157835,0.0003626068,0.000002132275,0.000004860218,0.00001112549,0.0002040867],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0049941,"threshold_uncertainty_score":0.3449623,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01608336084370198,"score_gpt":0.2268193304244305,"score_spread":0.2107359695807285,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}