{"id":"W2102401083","doi":"10.1002/chem.200501326","title":"The Interplay of Inverted Redox Potentials and Aromaticity in the Oxidized States of New π‐Electron Donors: 9‐(1,3‐Dithiol‐2‐ylidene)fluorene and 9‐(1,3‐Dithiol‐2‐ylidene)thioxanthene Derivatives","year":2006,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organic Chemistry Cycloaddition Reactions","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Dication; Dithiol; Chemistry; Fluorene; Crystallography; Electron paramagnetic resonance; Electrochemistry; Photochemistry; Molecule; Medicinal chemistry; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007834691,0.0001327981,0.00009789362,0.0000883121,0.0001123975,0.0002190584,0.0001746201,0.0002003011,0.0009168246],"category_scores_gemma":[0.0001281565,0.00008931066,0.00005720876,0.00008047822,0.0002160092,0.0002163216,0.0001086127,0.0003131749,0.0001185939],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001893417,"about_ca_system_score_gemma":0.00008637172,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003039826,"about_ca_topic_score_gemma":0.0006144594,"domain_scores_codex":[0.9999601,0.000007277878,0.000002057567,0.000008003139,0.00001057316,0.00001202863],"domain_scores_gemma":[0.999945,0.00002308859,0.00001135461,0.000004214581,0.000007192904,0.000009191412],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001202367,0.00002747424,0.0002807653,0.0000621866,0.000006338019,0.0001392925,0.00008884589,0.0001933516,0.9959688,0.001099038,0.00003766836,0.001976033],"study_design_scores_gemma":[0.00001446257,0.0002165282,0.002014806,0.000004546608,0.00001170294,0.0001450381,0.00005335496,0.001824233,0.9947774,0.0001726776,0.0007582781,0.000006986711],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982423,0.00020997,0.0003659956,0.00002151272,0.000004233356,0.000003230066,0.00002303525,0.000010107,0.001119665],"genre_scores_gemma":[0.9991999,0.0001533431,0.0002214104,0.000005783539,0.000001314231,0.000002813735,0.00002338934,0.00000234939,0.0003897296],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009168246,"threshold_uncertainty_score":0.003067136,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006035954418004435,"score_gpt":0.22011631459665,"score_spread":0.2140803601786456,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}