{"id":"W2102620946","doi":"10.1139/cjc-2014-0043","title":"Synthesis and structure of iron(III) complexes of amine-bis(phenolate) ligands","year":2014,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University; Memorial University of Newfoundland","funders":"","keywords":"Chemistry; Trigonal bipyramidal molecular geometry; Dimer; Isopropyl; Anhydrous; Ligand (biochemistry); Amine gas treating; Bromide; Medicinal chemistry; Lithium (medication); Methylene; Crystal structure; Stereochemistry; Polymer chemistry; Crystallography; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001844306,0.0001825205,0.0004901171,0.0000897475,0.00005243654,0.00002328571,0.0003780443,0.0001992083,0.002330362],"category_scores_gemma":[0.0004490601,0.0001763308,0.0001151068,0.000102459,0.0001702637,0.00008044897,0.000021372,0.0002516359,5.11264e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006645259,"about_ca_system_score_gemma":0.0004426496,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003548112,"about_ca_topic_score_gemma":0.0004042994,"domain_scores_codex":[0.9987119,0.0000112489,0.0006405918,0.0001507387,0.0002572607,0.0002282651],"domain_scores_gemma":[0.9980307,0.0001278264,0.0007339105,0.0003090484,0.0002792163,0.0005192771],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001569899,0.000007828861,0.0009090271,0.0004803533,0.00007142977,0.000009607455,0.0001856055,0.00002314223,0.9970423,0.00007826197,0.0002070978,0.0009696595],"study_design_scores_gemma":[0.0004680479,0.00001125913,0.0002553447,0.0001834171,0.00007970534,0.0001884884,0.0002964976,0.00004577329,0.9967766,0.0004841486,0.001060148,0.0001505362],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9956914,0.0004048516,0.00008562682,0.00008290862,0.00005805216,0.00001838266,0.0001664693,0.000004150217,0.003488207],"genre_scores_gemma":[0.9988967,0.00001491621,0.0005448495,0.00002033272,0.0001625148,4.825508e-7,0.00001441826,0.00002459674,0.0003212148],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003205322,"threshold_uncertainty_score":0.9985816,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007545027822937441,"score_gpt":0.1947990957218226,"score_spread":0.1872540678988852,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}