{"id":"W2102678387","doi":"10.1002/ejoc.200500863","title":"“On Water”‐Promoted Direct Coupling of Indoles with 1,4‐Benzoquinones without Catalyst","year":2005,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":96,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Chinese Academy of Sciences; National Natural Science Foundation of China","keywords":"Chemistry; Catalysis; Indole test; Direct coupling; Coupling (piping); Solvent; Organic chemistry; Oxidative coupling of methane; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000143306,0.0004886525,0.0002331143,0.0001422361,0.0001182971,0.0001755222,0.0003382695,0.0002145074,0.002297175],"category_scores_gemma":[0.0001607439,0.0002090243,0.0001961632,0.0001340272,0.0002385365,0.0003593657,0.0003077619,0.000490036,0.0006104416],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001811668,"about_ca_system_score_gemma":0.000186043,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008329962,"about_ca_topic_score_gemma":0.001569136,"domain_scores_codex":[0.9998203,0.0000281481,0.000006958538,0.00003743694,0.00004405571,0.00006312718],"domain_scores_gemma":[0.9999266,0.00001779171,0.00001752359,0.000007703798,0.00001254537,0.00001791426],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004479118,0.00001248166,0.00003032463,0.00006477181,0.000004396723,0.00004668842,0.00002790747,0.00004520297,0.9980974,0.0001290092,0.00007896803,0.001418218],"study_design_scores_gemma":[0.000004801434,0.00006524338,0.0001567703,0.000001636077,0.000004256533,0.00002389212,0.00000496127,0.00009583279,0.9982986,0.00001742101,0.001323635,0.000003002572],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9709069,0.001494081,0.0192782,0.0001227451,0.00009151127,0.00009254566,0.0002816333,0.0002358173,0.007496628],"genre_scores_gemma":[0.9871801,0.0008435378,0.004743824,0.00003600223,0.00001463971,0.00002664576,0.0002112729,0.00005826233,0.006885828],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002297175,"threshold_uncertainty_score":0.007684767,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008403328593966058,"score_gpt":0.2004086160479824,"score_spread":0.1920052874540163,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}