{"id":"W2102978517","doi":"10.1021/ac010784e","title":"Determination of Polybrominated Diphenyl Ethers and Polychlorinated Biphenyls in Human Adipose Tissue by Large-Volume Injection−Narrow-Bore Capillary Gas Chromatography/Electron Impact Low-Resolution Mass Spectrometry","year":2002,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Toxic Organic Pollutants Impact","field":"Environmental Science","cited_by":104,"is_retracted":false,"has_abstract":true,"ca_institutions":"Health Canada","funders":"","keywords":"Chemistry; Polybrominated diphenyl ethers; Resolution (logic); Chromatography; Extraction (chemistry); Mass spectrometry; Electron ionization; Selected ion monitoring; Gas chromatography; Detection limit; Adipose tissue; Solid phase extraction; Chemical ionization; Analytical Chemistry (journal); Gas chromatography–mass spectrometry; Ionization; Ion; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002671611,0.0003497691,0.0004003471,0.000147786,0.0001221013,0.00003821331,0.0002632789,0.0003234017,0.005903615],"category_scores_gemma":[0.0001318374,0.0003520024,0.0001118622,0.001340121,0.0004024336,0.0003019708,0.00008543274,0.0004104067,0.00003109442],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007278763,"about_ca_system_score_gemma":0.00001646511,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004876585,"about_ca_topic_score_gemma":0.00003582285,"domain_scores_codex":[0.9976296,0.00007055741,0.0005069822,0.0005554458,0.0004656854,0.0007716626],"domain_scores_gemma":[0.9990394,0.0000476891,0.0002035864,0.0003807497,0.000007506215,0.0003210486],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003238402,0.0002903439,0.02668966,0.00003256822,0.00003647145,0.00002629367,0.000186766,0.00001791781,0.9707162,0.000001797864,0.0006036272,0.001365953],"study_design_scores_gemma":[0.001478727,0.0004694667,0.1448248,0.00006427051,0.000110308,0.0001025705,0.0001076777,0.04541597,0.8063925,0.0002775186,0.0001032892,0.0006529515],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966894,0.0005048077,0.0001016299,0.0001237476,0.00002151866,0.0001650103,0.0001070608,0.00007127198,0.002215525],"genre_scores_gemma":[0.9990808,0.0000422852,0.00008606367,0.00002636107,0.00003276986,0.000003930673,0.00002436275,0.00004209761,0.0006613035],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1643237,"threshold_uncertainty_score":0.9998932,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005085215873974554,"score_gpt":0.2395386773546823,"score_spread":0.2344534614807077,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}