{"id":"W2103362663","doi":"10.1039/b314110a","title":"Reactions of N-heterocyclic carbenes (NHCs) with one-electron oxidants: possible formation of a carbene cation radicalElectronic supplementary information (ESI) available: spectroscopic data, calculated atomic coordinates and cyclic voltammograms. See http://www.rsc.org/suppdata/cc/b3/b314110a/","year":2004,"lang":"en","type":"article","venue":"Chemical Communications","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":71,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"","keywords":"Carbene; Chemistry; Electron; Computational chemistry; Physical chemistry; Organic chemistry; Physics; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002481915,0.0003181226,0.0001861766,0.0001587025,0.0001657172,0.0001657511,0.0003718683,0.0005219596,0.001916242],"category_scores_gemma":[0.000421832,0.00008037154,0.0001448212,0.0001076604,0.0002547185,0.0003528787,0.0001866884,0.0003504415,0.0001975198],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000254548,"about_ca_system_score_gemma":0.0001514761,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008996684,"about_ca_topic_score_gemma":0.001943785,"domain_scores_codex":[0.9998196,0.00003123447,0.00000768787,0.00004802958,0.00004393957,0.00004948846],"domain_scores_gemma":[0.9997807,0.0001021572,0.00003705084,0.00002262427,0.00002666217,0.00003073817],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002711582,0.00005404824,0.0005215968,0.0002456715,0.00001838275,0.0002856394,0.00008820429,0.0001961823,0.9920331,0.0009870724,0.0002484683,0.005050435],"study_design_scores_gemma":[0.00001546291,0.0001731357,0.0009420609,0.000006719328,0.000009493137,0.0001644315,0.0000243752,0.0003302382,0.9967723,0.00009045833,0.001466211,0.000005010248],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9906726,0.001612018,0.001598194,0.00008953489,0.00005698499,0.0000474074,0.0001349417,0.00001807524,0.005770132],"genre_scores_gemma":[0.997265,0.0003402205,0.0006197561,0.000027198,0.000008878722,0.000009762999,0.00009880141,0.00000323589,0.001627152],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001916242,"threshold_uncertainty_score":0.00641042,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01743644221626564,"score_gpt":0.2544538022164695,"score_spread":0.2370173600002039,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}