{"id":"W2103478370","doi":"10.1002/rcm.6560","title":"A miniature condensed‐phase membrane introduction mass spectrometry (CP‐MIMS) probe for direct and on‐line measurements of pharmaceuticals and contaminants in small, complex samples","year":2013,"lang":"en","type":"article","venue":"Rapid Communications in Mass Spectrometry","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"Vancouver Island University; University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; Vancouver Island University","keywords":"Chemistry; Analyte; Mass spectrometry; Chromatography; Analytical Chemistry (journal); Polydimethylsiloxane; Detection limit; Sample preparation; Electrospray; Triple quadrupole mass spectrometer; Tandem mass spectrometry; Selected reaction monitoring","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0009177831,0.0004456987,0.0008659385,0.001059886,0.0001992524,0.00009482037,0.000918814,0.0002793719,0.001546133],"category_scores_gemma":[0.0004431348,0.0004622834,0.0001165629,0.001433531,0.0004308672,0.0001832725,0.0002429476,0.0007292652,0.000004485851],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003407604,"about_ca_system_score_gemma":0.00005784981,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001237266,"about_ca_topic_score_gemma":0.00009902647,"domain_scores_codex":[0.9971153,0.0001814554,0.001036031,0.0007609648,0.0003085475,0.000597725],"domain_scores_gemma":[0.9964202,0.0009348703,0.0004377059,0.001834615,0.0002004205,0.0001722136],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001492695,0.001239346,0.007565452,0.0003624243,0.0001206768,8.41225e-7,0.00009878322,0.000003401366,0.9777651,0.008932023,0.0002628675,0.003499797],"study_design_scores_gemma":[0.008433246,0.0007989184,0.01203902,0.0003300383,0.0001899034,0.00003378877,0.0007123647,0.003979757,0.9450796,0.02235172,0.005024856,0.001026841],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9403214,0.007231982,0.01225911,0.0166649,0.0001135232,0.005413646,0.0008669855,0.0004662389,0.01666226],"genre_scores_gemma":[0.8419838,0.00265674,0.1538321,0.00009235071,0.00009422391,0.0009112559,0.0002452108,0.00005564452,0.0001287256],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.141573,"threshold_uncertainty_score":0.9997829,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1052858333233697,"score_gpt":0.3570564027360736,"score_spread":0.251770569412704,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}