{"id":"W2103548056","doi":"10.1021/om300759p","title":"Cleavage of Carbon Monoxide Promoted by a Dinuclear Tantalum Tetrahydride Complex","year":2012,"lang":"en","type":"article","venue":"Organometallics","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Carbon monoxide; Adduct; Tantalum; Cleavage (geology); Bond cleavage; Methane; Extrusion; Crystallography; Single crystal; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001937867,0.0002488212,0.0004273612,0.0001548495,0.00002808946,0.00001674562,0.000306948,0.0001473335,0.0006486699],"category_scores_gemma":[0.0002366035,0.0002654481,0.0001479937,0.0009044629,0.00009698908,0.0001643022,0.000142006,0.0001964965,0.00005803027],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001390437,"about_ca_system_score_gemma":0.00001527971,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006845077,"about_ca_topic_score_gemma":0.000003564962,"domain_scores_codex":[0.9984088,0.0000291143,0.0004597543,0.0002573784,0.0003821655,0.0004628118],"domain_scores_gemma":[0.9989136,0.00007997188,0.000178146,0.000531294,0.00006388922,0.0002330587],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000009702125,0.0001676092,0.004553196,0.00005967215,0.0001179642,0.000001002239,0.0002894676,0.00005128216,0.992975,0.0004478245,0.001035512,0.0002917762],"study_design_scores_gemma":[0.0004355486,0.00002439918,0.002426181,0.00001987591,0.0001369967,0.00001037549,0.0001180078,0.01110055,0.9736612,0.00001989856,0.01165589,0.0003910999],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9889529,0.0002672145,0.0009833686,0.00007569541,0.0001275974,0.0001937638,0.00007645244,0.0002497163,0.009073253],"genre_scores_gemma":[0.997148,0.00002680632,0.001323969,0.00004503048,0.00008991137,0.00001067365,0.0001322819,0.0001041885,0.001119107],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01931382,"threshold_uncertainty_score":0.9999798,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01659996964238622,"score_gpt":0.2298444895115188,"score_spread":0.2132445198691326,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}