{"id":"W2104586900","doi":"10.1021/jp807603t","title":"Dynamics of Si−H−Si Bridges in Agostically Stabilized Silylium Ions","year":2009,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Solid-state spectroscopy and crystallography","field":"Materials Science","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"","keywords":"Hydride; Silylation; Agostic interaction; Chemistry; Ion; Crystallography; Molecular dynamics; Internal rotation; Rotation (mathematics); Computational chemistry; Hydrogen; Metal; Organic chemistry; Catalysis; Geometry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001014369,0.0001912782,0.0001969199,0.0001304168,0.0003079118,0.0003146818,0.0003454087,0.0002218902,0.002827774],"category_scores_gemma":[0.0001648871,0.0001830225,0.000132809,0.00008120215,0.0004290684,0.0003993562,0.0003614703,0.000377876,0.0002092064],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003965676,"about_ca_system_score_gemma":0.0001899027,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007855922,"about_ca_topic_score_gemma":0.0009341292,"domain_scores_codex":[0.9999592,0.000003668377,0.000001335598,0.000008381925,0.000009647224,0.00001779875],"domain_scores_gemma":[0.9999362,0.000016809,0.00001691526,0.000003922075,0.000006264087,0.00001976614],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.0009081608,0.0001590127,0.001640044,0.0002047684,0.0000493664,0.000479489,0.001076207,0.01478284,0.9616625,0.008651759,0.0007709736,0.009614817],"study_design_scores_gemma":[0.0002557734,0.001803277,0.006290967,0.00004216088,0.00004842064,0.0002281103,0.0005865551,0.1131867,0.8702387,0.002215471,0.005027947,0.00007582838],"study_design_candidate":"simulation_or_modeling","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9986262,0.00007893117,0.0003198506,0.00002749062,0.0000075122,0.000003599388,0.00002175166,0.00002157482,0.0008930875],"genre_scores_gemma":[0.9988482,0.00005827868,0.0002468467,0.00001221449,0.000003068598,0.000005506688,0.0000526617,0.00001091178,0.0007622667],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002827774,"threshold_uncertainty_score":0.009459794,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006333896689435145,"score_gpt":0.260037480824764,"score_spread":0.2537035841353289,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}