{"id":"W2104695022","doi":"10.1002/ejic.201001165","title":"Using NMR and ESI‐MS to Probe the Mechanism of Silane Dehydrocoupling Catalyzed by Wilkinson's Catalyst","year":2010,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Chemistry; Catalysis; Silane; Medicinal chemistry; Proton NMR; Reaction mechanism; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000233612,0.000308498,0.0001738751,0.0002901869,0.0001123954,0.0002468096,0.0002331696,0.0002624121,0.001080574],"category_scores_gemma":[0.0002100258,0.0001353115,0.0001359406,0.0001510909,0.0002913906,0.0003190265,0.0001309505,0.0002631706,0.0002745282],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003016953,"about_ca_system_score_gemma":0.0001713474,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003466466,"about_ca_topic_score_gemma":0.0004789116,"domain_scores_codex":[0.9999242,0.0000103985,0.000004309855,0.00001893974,0.00002626971,0.00001593687],"domain_scores_gemma":[0.9998941,0.0000326836,0.00003752142,0.000007575499,0.00001253683,0.00001553861],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007357201,0.000006419045,0.0001786564,0.00002029358,0.000004201539,0.00006502324,0.00002230328,0.00008106084,0.9984396,0.0001940341,0.0000302098,0.0008846776],"study_design_scores_gemma":[0.000004592169,0.00004744861,0.0008145273,0.000001501068,0.000003616568,0.00007808775,0.00001136774,0.0009073131,0.9977468,0.00005565246,0.000324494,0.000004600721],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9899648,0.0006314802,0.006792092,0.00008291303,0.00002414695,0.0000272063,0.0003212249,0.0001804352,0.001975625],"genre_scores_gemma":[0.9944695,0.0002756433,0.003873347,0.00004050167,0.000006578161,0.00001907821,0.0001702624,0.00001610418,0.001128999],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001080574,"threshold_uncertainty_score":0.003614902,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008865804162238144,"score_gpt":0.2146598562555281,"score_spread":0.20579405209329,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}