{"id":"W2105054985","doi":"10.1039/c2cc16385c","title":"Bright electrochemiluminescence of iridium(iii) complexes","year":2012,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":139,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke; Western University","funders":"","keywords":"Electrochemiluminescence; Iridium; Chemistry; Organic chemistry; Chromatography; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000105052,0.00009902479,0.0001364044,0.00002370039,0.0000616908,0.000004420919,0.0004966399,0.00009545988,0.000001967406],"category_scores_gemma":[0.00007978166,0.00009000597,0.00009192019,0.0001429557,0.0003281278,0.000004599547,0.0002795327,0.0001001733,0.000002048611],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001148297,"about_ca_system_score_gemma":0.00001763793,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000744284,"about_ca_topic_score_gemma":0.000002048943,"domain_scores_codex":[0.9993746,0.0000308632,0.0002053573,0.0001234374,0.00007585316,0.0001898591],"domain_scores_gemma":[0.9986272,0.00002764119,0.00009766059,0.001068524,0.0001109337,0.000068038],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000009911373,0.0001204802,0.0008989355,0.000005059871,0.00002133884,1.736529e-8,0.00001398093,3.145018e-8,0.996546,0.0004097782,0.001252326,0.0007221381],"study_design_scores_gemma":[0.0000862823,0.00001280769,0.0002683905,0.000009670926,0.0000232487,0.000007145395,0.00002058095,0.00001172349,0.9805498,0.00008851517,0.01881135,0.0001104766],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9890143,0.002709531,0.002590888,0.0004397162,0.00001757797,0.0001108362,0.00001624887,0.00005375429,0.005047142],"genre_scores_gemma":[0.9788007,0.0004114804,0.02019415,0.0001137709,0.00007053038,0.000009205485,0.0002699184,0.000009969779,0.0001202991],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01760326,"threshold_uncertainty_score":0.3670337,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0198878900895008,"score_gpt":0.3043013209418996,"score_spread":0.2844134308523988,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}