{"id":"W2105220368","doi":"10.1039/c1sc00458a","title":"Palladium(0)-catalyzed cyclopropane C–H bond functionalization: synthesis of quinoline and tetrahydroquinoline derivatives","year":2011,"lang":"en","type":"article","venue":"Chemical Science","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":113,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Cyclopropane; Quinoline; Palladium; Intramolecular force; Chemistry; Surface modification; Catalysis; Bond cleavage; Medicinal chemistry; Ring (chemistry); Combinatorial chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001587203,0.0003575706,0.0001742118,0.0001504954,0.0001446849,0.000142174,0.0004147985,0.0002518539,0.001874678],"category_scores_gemma":[0.0001108711,0.0001215605,0.0001856841,0.000160566,0.0001816085,0.0001914158,0.0001497026,0.0003314679,0.000413891],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002240933,"about_ca_system_score_gemma":0.0002243109,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006860442,"about_ca_topic_score_gemma":0.001112269,"domain_scores_codex":[0.9999114,0.00001230452,0.000007671671,0.00002282723,0.00002036451,0.00002543543],"domain_scores_gemma":[0.9999497,0.000006298143,0.00001314055,0.000007451868,0.00001094814,0.00001252716],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007899362,0.00003898686,0.00008314136,0.0001203411,0.000009771919,0.0001242533,0.00002853501,0.0002803517,0.9934174,0.0004249084,0.000164133,0.005229185],"study_design_scores_gemma":[0.0000185218,0.0002950626,0.0004368841,0.000003230276,0.000008562756,0.0002191577,0.000007935441,0.0002970081,0.995067,0.00005053368,0.003589117,0.000007033355],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.9434376,0.003691403,0.03577127,0.0002054497,0.00008432299,0.0002768657,0.0008408197,0.0003346079,0.01535766],"genre_scores_gemma":[0.9830886,0.001329084,0.01116806,0.0000602874,0.000008542072,0.0000544964,0.0003068826,0.00002211336,0.003961958],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.001874678,"threshold_uncertainty_score":0.006271422,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03292010763385612,"score_gpt":0.2667841743040064,"score_spread":0.2338640666701503,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}