{"id":"W2105823149","doi":"10.1002/chir.20822","title":"Chiral discrimination in diastereomeric salts of chlorine‐substituted mandelic acid and phenylethylamine","year":2010,"lang":"en","type":"article","venue":"Chirality","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Diastereomer; Chirality (physics); van der Waals force; Hydrogen bond; Chlorine atom; Mandelic acid; Chlorine; Crystal structure; Stereochemistry; Organic chemistry; Medicinal chemistry; Molecule; Chiral symmetry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002292493,0.0002661095,0.0003829269,0.000145632,0.000183726,0.0005765103,0.0004000247,0.0002949141,0.0008490442],"category_scores_gemma":[0.0006395259,0.0002142198,0.0001125471,0.0002066548,0.0003759062,0.0001863201,0.0001668549,0.0005819064,0.0002782372],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003996662,"about_ca_system_score_gemma":0.0004372062,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001846208,"about_ca_topic_score_gemma":0.002618424,"domain_scores_codex":[0.9998155,0.00003628938,0.00001314194,0.00003399271,0.00006824185,0.00003276091],"domain_scores_gemma":[0.9997191,0.00008182698,0.00007192084,0.00002043945,0.00004224309,0.00006457601],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001460507,0.00001814749,0.0003599967,0.00003721903,0.000006242951,0.00007540012,0.00004070345,0.000207674,0.9973399,0.0002599188,0.00005816599,0.001450477],"study_design_scores_gemma":[0.0000439668,0.0001263623,0.0007769121,0.000004261317,0.000007127371,0.0001053059,0.00002938929,0.001434928,0.9966556,0.00004459287,0.0007634629,0.000008106185],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973063,0.0002724148,0.0006479212,0.00004865713,0.00001222123,0.00001065403,0.00008216614,0.00002855933,0.001591131],"genre_scores_gemma":[0.9957815,0.000259699,0.002472626,0.00003496831,0.000005132684,0.00001360062,0.0001704989,0.00002168875,0.001240194],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001846208,"threshold_uncertainty_score":0.003670871,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01077238000057402,"score_gpt":0.2524113621342356,"score_spread":0.2416389821336616,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}