{"id":"W2105823149","doi":"10.1002/chir.20822","title":"Chiral discrimination in diastereomeric salts of chlorine‐substituted mandelic acid and phenylethylamine","year":2010,"lang":"en","type":"article","venue":"Chirality","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Diastereomer; Chirality (physics); van der Waals force; Hydrogen bond; Chlorine atom; Mandelic acid; Chlorine; Crystal structure; Stereochemistry; Organic chemistry; Medicinal chemistry; Molecule; Chiral symmetry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007957144,0.0001139923,0.0001579316,0.00008380814,0.00003624861,0.00001479792,0.00009278602,0.00008013035,0.0001746064],"category_scores_gemma":[0.00007355113,0.0001105308,0.00006605813,0.0001477543,0.0001195627,0.0001192379,0.00004775067,0.0002647671,0.00000105299],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000009964544,"about_ca_system_score_gemma":0.00001211627,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002073274,"about_ca_topic_score_gemma":0.001047228,"domain_scores_codex":[0.9993009,0.00001043465,0.0002428595,0.0002046114,0.00009862342,0.000142571],"domain_scores_gemma":[0.9995546,0.00001974475,0.00009131535,0.0002498846,0.00003228432,0.00005219329],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.00004192732,0.000161759,0.02273128,0.0001310628,0.00001631458,0.000004680374,0.0003488908,0.000001594102,0.9703249,0.0009334657,0.000007025886,0.005297144],"study_design_scores_gemma":[0.00130306,0.0000275118,0.5037076,0.00006889266,0.00003974403,0.00002525881,0.000283949,0.0001725587,0.4914215,0.001195348,0.001471858,0.0002827203],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9938822,0.00005452609,0.0001168036,0.00009248376,0.0001621926,0.00005788627,0.0000327722,0.00002849119,0.005572631],"genre_scores_gemma":[0.9995008,0.00001913663,0.0001807675,0.00001781831,0.00005946151,0.00001724499,0.00008122477,0.000008740139,0.0001148281],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4809763,"threshold_uncertainty_score":0.4507317,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01077238000057402,"score_gpt":0.2524113621342356,"score_spread":0.2416389821336616,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}