{"id":"W2106631634","doi":"10.1021/jo051318i","title":"Studies toward the Total Synthesis of Vinigrol. Synthesis of the Octalin Ring","year":2005,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Cyclooctane; Ring (chemistry); Ring-closing metathesis; Stereochemistry; Total synthesis; Chemistry; Metathesis; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.002545593,0.0004067639,0.0009091063,0.00002393587,0.0001808406,0.0000215501,0.002267241,0.0002393349,0.003116612],"category_scores_gemma":[0.009196282,0.0002116407,0.0005728732,0.0003852486,0.0008040242,0.00008817794,0.0005997497,0.0008571128,0.000005583352],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002889885,"about_ca_system_score_gemma":0.0003365704,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006621763,"about_ca_topic_score_gemma":0.000001404486,"domain_scores_codex":[0.9966513,0.0001899279,0.001529524,0.0002353329,0.0009959018,0.0003980221],"domain_scores_gemma":[0.9911479,0.004903002,0.002014821,0.001407998,0.0004173208,0.0001089954],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001113974,0.0001402316,0.0001745345,0.0005672953,0.0007748597,0.000003464166,0.001700344,0.00005913368,0.9905929,0.000002526082,0.000249672,0.005623638],"study_design_scores_gemma":[0.0003241184,0.00000842944,0.0001325477,0.0009238563,0.0009302064,0.001129417,0.008719401,0.00004243455,0.9872544,0.0001088798,0.000215283,0.0002110016],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9884434,0.003609244,0.00004493003,0.003994973,0.0001611869,0.00006699787,0.00002922109,0.00002309835,0.003626925],"genre_scores_gemma":[0.9970841,0.0007849515,0.000670923,0.0000290471,0.0008440551,0.000005158932,2.009992e-7,0.00006807886,0.0005134314],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00864073,"threshold_uncertainty_score":0.9991497,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02452997621273728,"score_gpt":0.2784827317712492,"score_spread":0.2539527555585119,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}