{"id":"W2106651181","doi":"10.1002/ejic.201100080","title":"Formation and Reactivity of a Biomimetic Hydroperoxocopper(II) Cryptate","year":2011,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"Concordia University","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies; Deutsche Forschungsgemeinschaft","keywords":"Chemistry; Cryptand; Copper; Ligand (biochemistry); Reactivity (psychology); Hydroxylation; Photochemistry; Medicinal chemistry; Inorganic chemistry; Stereochemistry; Polymer chemistry; Organic chemistry; Ion; Enzyme","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008403521,0.0002015123,0.0001217218,0.00007982267,0.0001101529,0.0002247414,0.0002146621,0.0002378522,0.0009770991],"category_scores_gemma":[0.0001279984,0.00009541309,0.00007437707,0.00007263644,0.0001653443,0.0001532416,0.0001797429,0.0002092361,0.0001587349],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002963278,"about_ca_system_score_gemma":0.0001144788,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005718303,"about_ca_topic_score_gemma":0.0004955695,"domain_scores_codex":[0.9999357,0.00000622579,0.000002412306,0.00001871589,0.00001417472,0.00002271424],"domain_scores_gemma":[0.9999496,0.00000617142,0.00001753596,0.000005686192,0.000006194528,0.0000148578],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003406277,0.00003182091,0.0004236234,0.00007631547,0.00001330079,0.0002017096,0.00004240961,0.0005034423,0.9955807,0.0004199619,0.0001532236,0.00221286],"study_design_scores_gemma":[0.00002532515,0.0002728729,0.001189453,0.000004127745,0.000007979598,0.0001754757,0.00001986973,0.00129658,0.9954178,0.00009572271,0.001487858,0.000006959046],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9977409,0.0003022583,0.0007803135,0.0000280958,0.000009363922,0.000008842328,0.0000842732,0.00002823739,0.00101778],"genre_scores_gemma":[0.998611,0.00008509268,0.0004788616,0.000009252332,0.000002321817,0.00000313794,0.00007152803,0.000003362712,0.0007354301],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009770991,"threshold_uncertainty_score":0.003268719,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02324328179379527,"score_gpt":0.2041831384665479,"score_spread":0.1809398566727527,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}