{"id":"W2106944732","doi":"10.1351/pac200577071259","title":"Asymmetric catalytic addition of diorganozinc reagents to imines: Scope and application","year":2005,"lang":"en","type":"article","venue":"Pure and Applied Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Scope (computer science); Reagent; Catalysis; Combinatorial chemistry; Ligand (biochemistry); Copper; Monoxide; Enantioselective synthesis; Organic chemistry; Biochemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007789542,0.0001657191,0.0002190481,0.00007971398,0.00006941497,0.00002343724,0.0001321586,0.000140498,0.0002106817],"category_scores_gemma":[0.00004356137,0.0001696176,0.00003643126,0.0005576522,0.00005013184,0.00005065231,0.00008291886,0.0001001189,0.00002933663],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004593496,"about_ca_system_score_gemma":0.00002132803,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000631461,"about_ca_topic_score_gemma":0.0000017323,"domain_scores_codex":[0.9989575,0.000001809505,0.0002834862,0.0003651726,0.0002241774,0.0001678483],"domain_scores_gemma":[0.9993153,0.0000402163,0.0001352159,0.0002869116,0.00004871457,0.0001736945],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000229512,0.000103473,0.0002182581,0.0003179993,0.00005355966,5.175207e-7,0.0001045491,0.0000165834,0.711931,0.00009650349,0.001463064,0.2856715],"study_design_scores_gemma":[0.0004052714,0.000003364126,0.0001384513,0.00001658038,0.00007533223,0.000008982526,0.0001389386,0.0001587986,0.9792663,0.00004457993,0.01955646,0.0001869445],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8797758,0.001085911,0.001029236,0.0002796157,0.000008053043,0.0001626762,0.0001290365,0.00009068481,0.117439],"genre_scores_gemma":[0.9978832,0.0001501424,0.0003367187,0.00009853617,0.0001612467,0.00007298437,0.0003655357,0.00001969883,0.0009119164],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2854846,"threshold_uncertainty_score":0.6916803,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004450964007371654,"score_gpt":0.2106800090215176,"score_spread":0.2062290450141459,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}