{"id":"W2107386667","doi":"10.1002/cctc.201200540","title":"Clean, Convenient, High‐yield Access to Second‐generation Ru Metathesis Catalysts from Commercially Available Precursors","year":2012,"lang":"en","type":"article","venue":"ChemCatChem","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Catalysis; Yield (engineering); Phosphine; Ruthenium; Metathesis; Olefin metathesis; IMes; Ligand (biochemistry); Chemistry; Filtration (mathematics); Grubbs' catalyst; Combinatorial chemistry; Organic chemistry; Ring-opening metathesis polymerisation; Carbene; Materials science; Polymerization","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0005750342,0.000511452,0.0006480769,0.00005664638,0.0001660643,0.0001804702,0.001086989,0.0004216155,0.03908991],"category_scores_gemma":[0.0008667574,0.0005489695,0.0001942418,0.0003437496,0.00008959228,0.0004887998,0.0004520548,0.0003812764,0.00135288],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003288952,"about_ca_system_score_gemma":0.0001477564,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005190276,"about_ca_topic_score_gemma":0.0001179001,"domain_scores_codex":[0.9972292,0.00005089643,0.0006329408,0.0007949488,0.0004646745,0.0008273476],"domain_scores_gemma":[0.9969335,0.0005555004,0.0002928648,0.001447594,0.0001393745,0.0006312227],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003641393,0.0002318034,0.003189119,0.00009718624,0.0001691511,0.000002432432,0.00122324,5.344473e-7,0.9177551,0.00001285641,0.07031304,0.006969101],"study_design_scores_gemma":[0.0004251818,0.000006876749,0.0004852611,0.00005680731,0.000203894,0.000009021613,0.000331289,0.00001435694,0.9533755,0.00005425335,0.04443729,0.0006002538],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9685912,0.0004294959,0.0002905872,0.0007486654,0.0006450938,0.0001888914,0.0002286965,0.0002587386,0.0286187],"genre_scores_gemma":[0.9775732,0.00002044206,0.008118098,0.0006084726,0.001964767,0.0001378231,0.0003868205,0.0001335478,0.01105683],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03773703,"threshold_uncertainty_score":0.9996962,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0864191731778281,"score_gpt":0.3024811161847797,"score_spread":0.2160619430069516,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}