{"id":"W2107402632","doi":"10.1007/0-306-46881-6_123","title":"The effects of stereochemistry and sequence on 5-t-butylproline type VI β-turn mimics","year":2006,"lang":"en","type":"book-chapter","venue":"Kluwer Academic Publishers eBooks","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Steric effects; Chemistry; Amide; Stereochemistry; Turn (biochemistry); Peptide; Proline; Substituent; Nuclear magnetic resonance spectroscopy; Amino acid; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002425598,0.0004362251,0.0004359191,0.00005222393,0.0001005482,0.00009103954,0.0005739882,0.001221978,0.00001176365],"category_scores_gemma":[0.0003243693,0.0003255572,0.0002399034,0.00002372119,0.0004398728,0.000007028405,0.0002580281,0.0008440921,0.000002980546],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004000524,"about_ca_system_score_gemma":0.0001065989,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000122423,"about_ca_topic_score_gemma":0.000004327335,"domain_scores_codex":[0.9981872,0.00002509522,0.0004919821,0.0006274505,0.0003300281,0.0003381894],"domain_scores_gemma":[0.9985147,0.0001643393,0.0004092053,0.000612423,0.0001571193,0.0001421848],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0001571519,0.0000177556,0.00008095161,0.0002873498,0.0004440997,0.000008625892,0.00001681117,0.000001788772,0.885242,0.0008643724,0.09254792,0.02033115],"study_design_scores_gemma":[0.0003667497,0.0001499914,0.00001173662,0.0002992245,0.0002457619,0.00001535041,0.000007125426,0.00001324058,0.4047257,0.002443742,0.5912158,0.0005055331],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.1198351,0.01184842,0.00003051952,0.0005867669,0.0005412453,0.0006708089,0.0001501172,0.00005439464,0.8662827],"genre_scores_gemma":[0.3013504,0.001200962,0.00006293197,0.0007801887,0.001111417,0.00002782202,0.0003965208,0.0001443399,0.6949254],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.4986679,"threshold_uncertainty_score":0.9999197,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009295903036467459,"score_gpt":0.228581996299362,"score_spread":0.2192860932628946,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}