{"id":"W2107459410","doi":"10.1002/anie.201003074","title":"Catalytic Solvolysis of Ammonia Borane","year":2010,"lang":"de","type":"article","venue":"Angewandte Chemie International Edition","topic":"Hydrogen Storage and Materials","field":"Materials Science","cited_by":90,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Princess Margaret Cancer Centre","funders":"","keywords":"Ammonia borane; Solvolysis; Catalysis; Chemistry; Iridium; Ammonia; Borane; Hydrogen; Inorganic chemistry; Hydrogen production; Organic chemistry; Hydrolysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001950166,0.0005154059,0.0004142743,0.0001747452,0.0001457589,0.0002010741,0.0005122823,0.0003262264,0.001647961],"category_scores_gemma":[0.0001703353,0.0001826558,0.0001992855,0.0001534793,0.0002419955,0.0004331547,0.0006421764,0.0005695807,0.0006939367],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001997423,"about_ca_system_score_gemma":0.0002264143,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003707127,"about_ca_topic_score_gemma":0.0008523807,"domain_scores_codex":[0.999781,0.00002592315,0.00001126788,0.00005007614,0.00007072057,0.00006105252],"domain_scores_gemma":[0.9999452,0.00001127373,0.00001172759,0.000007098557,0.00001160562,0.00001319471],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003818925,0.000008647715,0.00003728237,0.00007684776,0.00000528342,0.00004435171,0.00001876418,0.00003259166,0.9975722,0.00005915816,0.0000684679,0.002038247],"study_design_scores_gemma":[0.000006230553,0.0000481053,0.0001465189,0.000002753802,0.000003286219,0.00006810675,0.000007948566,0.0002715137,0.9985749,0.00001167969,0.0008561201,0.000002833498],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9704095,0.00159661,0.02040051,0.0001432671,0.00006956307,0.0001241179,0.0004990285,0.0005028095,0.006254526],"genre_scores_gemma":[0.985707,0.001255755,0.007794059,0.00005727926,0.00002263205,0.0000740877,0.0006163153,0.0001046503,0.004368255],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001647961,"threshold_uncertainty_score":0.005512953,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01081100039923072,"score_gpt":0.2582126860294172,"score_spread":0.2474016856301864,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}