{"id":"W2107584439","doi":"10.1139/v03-050","title":"Benzotriazolium ylides: Experimental and theoretical study on the tautomeric equilibrium of monosubstituted benzotriazolium ylides","year":2003,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis and Reactions of Organic Compounds","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Tautomer; Chemistry; Triethylamine; Computational chemistry; Reactivity (psychology); Kinetics; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004202621,0.0002575924,0.0004292199,0.00009051371,0.0001649529,0.00009329301,0.0004543781,0.0001484994,0.002980833],"category_scores_gemma":[0.0007076571,0.0001884369,0.0001778903,0.0001924409,0.0005056017,0.00008878957,0.00002426831,0.0004380874,0.000003250068],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000187293,"about_ca_system_score_gemma":0.0008175427,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001675836,"about_ca_topic_score_gemma":0.00002468846,"domain_scores_codex":[0.9984341,0.00004761947,0.000625636,0.0002250502,0.0003176472,0.0003499253],"domain_scores_gemma":[0.9981285,0.000386692,0.0003699893,0.000455827,0.0001436056,0.0005153443],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006419881,0.0002991036,0.003294074,0.00003944389,0.0002652754,0.00009995087,0.0008561469,0.00001138859,0.9928432,0.001219252,0.0008458202,0.0001622216],"study_design_scores_gemma":[0.0008684091,0.00008195804,0.0005689433,0.0001016022,0.00008422985,0.0004209395,0.01048699,0.00001412938,0.9848819,0.0003059325,0.001969758,0.0002151606],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9807348,0.001161717,0.000003544422,0.0003437897,0.000189502,0.00007330417,0.00001784552,0.000009431787,0.01746605],"genre_scores_gemma":[0.9994984,0.00001136664,0.00003223621,0.00003597415,0.0002209304,0.000005405708,0.000001536102,0.00003199024,0.0001621254],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01876362,"threshold_uncertainty_score":0.9979306,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01496590185215033,"score_gpt":0.2323009449540571,"score_spread":0.2173350431019067,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}