{"id":"W2107889383","doi":"10.1039/c5sc03575a","title":"Mechanistic studies on the addition of hydrogen to iridaepoxide complexes with subsequent elimination of water","year":2015,"lang":"en","type":"article","venue":"Chemical Science","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"Calgary Laboratory Services; University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Alberta Innovates; Alberta Innovates - Technology Futures","keywords":"Chemistry; Iridium; Reductive elimination; Ligand (biochemistry); Elimination reaction; Combinatorial chemistry; Carbene; Hydrogen; Stereochemistry; Catalysis; Medicinal chemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000640819,0.00007453968,0.0001205062,0.00003836663,0.0000464106,0.000008769441,0.0002320325,0.00002132991,0.0001626922],"category_scores_gemma":[0.001373051,0.00004059172,0.00002095172,0.0002905592,0.0004776825,0.00005511496,0.00009297536,0.00004393253,0.00001088078],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001663019,"about_ca_system_score_gemma":0.00006845497,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000908326,"about_ca_topic_score_gemma":0.000001542291,"domain_scores_codex":[0.99884,0.00001101891,0.0002017241,0.0001975244,0.0006231551,0.0001265548],"domain_scores_gemma":[0.998963,0.0001953346,0.00008712073,0.0002238282,0.0004515892,0.0000791435],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003228951,0.00003100156,0.00002159818,0.0000246361,0.000007264367,3.137253e-7,0.0004505247,0.0003177951,0.9924068,0.006400314,0.0002038684,0.0001035663],"study_design_scores_gemma":[0.000110947,0.00003046287,0.00002304861,0.00005117635,0.00001394359,0.000004423773,0.0004917906,0.0005123621,0.995524,0.003037336,0.0001411056,0.00005933103],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961892,0.000008184348,0.001591314,0.0005445593,0.00003557486,0.00006898257,0.00001662498,0.00001526881,0.001530262],"genre_scores_gemma":[0.9982678,5.673617e-7,0.001473386,0.00007594349,0.00002852528,0.00002009085,0.00001954662,0.00000471633,0.0001094568],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003362979,"threshold_uncertainty_score":0.1781366,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08383070388326273,"score_gpt":0.3240531205759735,"score_spread":0.2402224166927108,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}