{"id":"W2107889383","doi":"10.1039/c5sc03575a","title":"Mechanistic studies on the addition of hydrogen to iridaepoxide complexes with subsequent elimination of water","year":2015,"lang":"en","type":"article","venue":"Chemical Science","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"Calgary Laboratory Services; University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Alberta Innovates; Alberta Innovates - Technology Futures","keywords":"Chemistry; Iridium; Reductive elimination; Ligand (biochemistry); Elimination reaction; Combinatorial chemistry; Carbene; Hydrogen; Stereochemistry; Catalysis; Medicinal chemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002304278,0.0003455136,0.0002164701,0.00008397482,0.0002259758,0.0002503791,0.0005478473,0.0003698698,0.003395557],"category_scores_gemma":[0.0002531776,0.0001479645,0.0001796759,0.0001020988,0.0003667705,0.0005218757,0.0002384528,0.0005867341,0.0003629377],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003135821,"about_ca_system_score_gemma":0.0001941417,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006390781,"about_ca_topic_score_gemma":0.0009596472,"domain_scores_codex":[0.9998811,0.00001696347,0.000004637343,0.0000213858,0.00002706743,0.00004877554],"domain_scores_gemma":[0.9999362,0.00002245409,0.00001478883,0.000009472889,0.000009501462,0.000007553612],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001549854,0.0005540336,0.0006064367,0.0006429772,0.00006783124,0.0004556153,0.0004673531,0.002777448,0.9678369,0.008907401,0.0008895304,0.01524464],"study_design_scores_gemma":[0.00006823507,0.0005297433,0.0008944722,0.00001103986,0.00001585975,0.00009455036,0.00007322629,0.001954668,0.993041,0.0003347434,0.002971171,0.00001128287],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9869283,0.0006760861,0.00308122,0.0001804028,0.00003002249,0.000109878,0.0001320249,0.00006471297,0.008797355],"genre_scores_gemma":[0.9972376,0.0004436088,0.0007911415,0.00003865988,0.000004295714,0.00003193946,0.00005251685,0.000005956806,0.001394252],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003395557,"threshold_uncertainty_score":0.01135927,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08383070388326273,"score_gpt":0.3240531205759735,"score_spread":0.2402224166927108,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}