{"id":"W2108073196","doi":"10.1002/anie.200802147","title":"Agostic NSiH⋅⋅⋅Mo Complexes: From Curiosity to Catalysis","year":2008,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":46,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"","keywords":"Agostic interaction; Reactivity (psychology); Chemistry; Hydrosilylation; Hydride; Trigonal bipyramidal molecular geometry; Catalysis; Silylation; Crystallography; Stereochemistry; Crystal structure; Organic chemistry; Metal","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002429352,0.0003761406,0.0003210393,0.0001788841,0.0002517848,0.0006261691,0.0004326102,0.0003617721,0.001802413],"category_scores_gemma":[0.0002946142,0.0002602284,0.0001417201,0.0001067746,0.0005530147,0.0007667427,0.001056353,0.0008487247,0.0006963906],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006575465,"about_ca_system_score_gemma":0.0001859577,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003034753,"about_ca_topic_score_gemma":0.0006492133,"domain_scores_codex":[0.9998621,0.00001634264,0.000009682877,0.00002808843,0.00004906859,0.0000347568],"domain_scores_gemma":[0.9999409,0.00001212046,0.00000882636,0.00001440331,0.000007860201,0.00001593736],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003839366,0.00008526836,0.0004402912,0.0007133504,0.00005706604,0.0006381523,0.0006280657,0.001294224,0.8141643,0.1179022,0.004580685,0.05911239],"study_design_scores_gemma":[0.00005156664,0.0002621234,0.0003106257,0.00004465607,0.0000236847,0.0006279264,0.0001046642,0.002046956,0.8738768,0.01149489,0.1111217,0.00003449533],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8010578,0.03829551,0.05494717,0.004791765,0.0009723466,0.0002063118,0.0002979337,0.001627,0.09780432],"genre_scores_gemma":[0.9749791,0.006342198,0.003953548,0.0002939527,0.00009485013,0.00004702319,0.00009588458,0.00009046236,0.01410296],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001802413,"threshold_uncertainty_score":0.006029665,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01779590216644109,"score_gpt":0.2467380734739768,"score_spread":0.2289421713075357,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}