{"id":"W2108308174","doi":"10.1002/chin.200709091","title":"Direct‐Type Catalytic Three‐Component Mannich Reaction in Aqueous Media.","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Chemistry; Aqueous medium; Catalysis; Component (thermodynamics); Aqueous solution; Combinatorial chemistry; Mannich reaction; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002507138,0.0008044319,0.000456942,0.0003170925,0.0004621207,0.0004639773,0.0008424376,0.000375703,0.003907371],"category_scores_gemma":[0.0002808655,0.0002096097,0.0002507599,0.0004575937,0.0003094899,0.001118303,0.001110144,0.0009413703,0.001763698],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000695599,"about_ca_system_score_gemma":0.0006673794,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001583888,"about_ca_topic_score_gemma":0.002722632,"domain_scores_codex":[0.999767,0.00003329254,0.00000968772,0.0000522212,0.0000599392,0.00007784128],"domain_scores_gemma":[0.9999595,0.000007297876,0.000007040354,0.000006620489,0.000006142744,0.00001334423],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009393435,0.0003048319,0.0003895179,0.001398274,0.0001887236,0.0008398303,0.0005578871,0.003527905,0.8196606,0.04223279,0.01662627,0.1133342],"study_design_scores_gemma":[0.00006343837,0.0004602431,0.0003434216,0.00004094693,0.00004292733,0.0003998095,0.0000786354,0.003834882,0.9545141,0.003116053,0.03704142,0.00006409745],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6351476,0.01179834,0.2050976,0.001421964,0.001478337,0.0007574847,0.001661702,0.004101572,0.1385354],"genre_scores_gemma":[0.9439406,0.005049623,0.02024369,0.0001265956,0.00005458629,0.000104187,0.0004817816,0.0001340761,0.02986488],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003907371,"threshold_uncertainty_score":0.01307148,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01590842730651858,"score_gpt":0.2397219455113562,"score_spread":0.2238135182048376,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}