{"id":"W2108308174","doi":"10.1002/chin.200709091","title":"Direct‐Type Catalytic Three‐Component Mannich Reaction in Aqueous Media.","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Chemistry; Aqueous medium; Catalysis; Component (thermodynamics); Aqueous solution; Combinatorial chemistry; Mannich reaction; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001916499,0.0001720735,0.0002188388,0.00006567816,0.00005294411,0.00001793703,0.0001688642,0.0002284784,0.0004273489],"category_scores_gemma":[0.0002035874,0.0001542221,0.0000878641,0.0002153611,0.00005451548,0.0001121929,0.00005585598,0.0002864423,0.0001553866],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004079904,"about_ca_system_score_gemma":0.00003325413,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003134909,"about_ca_topic_score_gemma":0.0004334738,"domain_scores_codex":[0.998785,1.354143e-7,0.0003736922,0.0002252364,0.000239632,0.00037626],"domain_scores_gemma":[0.9991291,0.0002431615,0.0001024155,0.0003320895,0.00004309063,0.0001501794],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006752928,0.0001459718,0.0006287755,0.00007576706,0.00002441992,0.0000254017,0.0002289865,1.98254e-7,0.6654064,0.00003536192,0.0014839,0.3318773],"study_design_scores_gemma":[0.0002432986,0.000003189828,0.00231625,0.00006088483,0.00001829163,0.00003279981,0.0001580315,0.00002131621,0.9162913,0.00007381642,0.08058041,0.0002004003],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.3796487,0.000233164,6.544799e-7,0.00005640927,0.0001398766,0.00003814411,0.000004457991,0.00009220828,0.6197864],"genre_scores_gemma":[0.9952099,0.00008450023,0.00003062611,0.00002887343,0.0002942546,0.000009649746,0.0001171402,0.00002213809,0.004202961],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6155835,"threshold_uncertainty_score":0.6288995,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01590842730651858,"score_gpt":0.2397219455113562,"score_spread":0.2238135182048376,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}