{"id":"W2108310199","doi":"10.1021/jo801856n","title":"Carbanionic Friedel−Crafts Equivalents. Regioselective Directed <i>Ortho</i> and Remote Metalation−C−N Cross Coupling Routes to Acridones and Dibenzo[<i>b</i>,<i>f</i>]azepinones","year":2008,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Coordination Chemistry and Organometallics","field":"Chemistry","cited_by":55,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University; Queen's University","funders":"","keywords":"Regioselectivity; Chemistry; Metalation; Acridone; Kinetic control; Desmethyl; Stereochemistry; Carbanion; Xanthone; Computational chemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001282254,0.000507329,0.0002406853,0.000199683,0.0001750071,0.0002109892,0.0005164391,0.0002674367,0.005735661],"category_scores_gemma":[0.0001240544,0.000147488,0.0002176691,0.0001759891,0.0001810555,0.0003110319,0.000316385,0.0006058946,0.001484717],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004728675,"about_ca_system_score_gemma":0.0003021029,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001155776,"about_ca_topic_score_gemma":0.002394842,"domain_scores_codex":[0.9998976,0.000007688396,0.000007939536,0.00002650086,0.00002639893,0.0000338507],"domain_scores_gemma":[0.9999526,0.000004884226,0.00001071826,0.00001135112,0.000008173574,0.00001226132],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003111962,0.0002992782,0.000293289,0.0007731493,0.0000536671,0.0004981424,0.0002310564,0.002146733,0.9525245,0.01663285,0.002262099,0.02397403],"study_design_scores_gemma":[0.0001772685,0.002269385,0.00196548,0.00003348851,0.00003758218,0.0008552353,0.00004276894,0.003502646,0.948062,0.0009597155,0.04204151,0.00005291827],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9042661,0.00354191,0.02352973,0.0002277273,0.0002721031,0.0004773163,0.00163856,0.0007263414,0.06532019],"genre_scores_gemma":[0.9716907,0.002121879,0.01116353,0.000113478,0.00002013448,0.0001558683,0.00089431,0.00004960563,0.01379042],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005735661,"threshold_uncertainty_score":0.01918769,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01641014379655437,"score_gpt":0.2475428991145371,"score_spread":0.2311327553179827,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}