{"id":"W2108871623","doi":"10.1002/ejic.200901126","title":"Reactivity Pattern in the Room‐Temperature Activation of NH<sub>3</sub> by the Main‐Group Atomic Ions Ga<sup>+</sup>, Ge<sup>+</sup>, As<sup>+</sup> and Se<sup>+</sup>","year":2010,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Ammonia Synthesis and Nitrogen Reduction","field":"Chemical Engineering","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Reactivity (psychology); Ion; Ammonia; Kinetic energy; Proton; Activation energy; Hydrogen; Chemical kinetics; Kinetics; Hydrogen atom; Yield (engineering); Physical chemistry; Inorganic chemistry; Analytical Chemistry (journal); Group (periodic table); Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity"],"consensus_categories":[],"category_scores_codex":[0.002522792,0.0009610111,0.0009982742,0.000184863,0.0004397695,0.000273664,0.001469237,0.0005090477,0.000375212],"category_scores_gemma":[0.0009522931,0.0007191726,0.0005249963,0.0007516357,0.0003585196,0.0007080504,0.0003345012,0.004325666,0.00005175288],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003574642,"about_ca_system_score_gemma":0.0002342779,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006056617,"about_ca_topic_score_gemma":0.000004785321,"domain_scores_codex":[0.9946265,0.000707894,0.001730628,0.00086992,0.001117251,0.0009477899],"domain_scores_gemma":[0.9960957,0.0007938803,0.001058292,0.001291342,0.0003178318,0.000442911],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002219777,0.0004298688,0.000971354,0.0002040236,0.0002702339,0.00009864871,0.003953427,0.003758749,0.9816937,0.0000173434,0.003750745,0.00462996],"study_design_scores_gemma":[0.001986695,0.0001382739,0.001036827,0.000523666,0.0002654771,0.002147481,0.005663314,0.01342656,0.9708043,0.00005469294,0.003121988,0.0008307586],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960353,0.0004629683,0.0003072166,0.001695598,0.00008779379,0.0003784838,0.0001282931,0.00009124849,0.0008130884],"genre_scores_gemma":[0.9970937,0.0002746902,0.0001503872,0.0003196779,0.001630688,0.00001492875,0.00008425592,0.0002482392,0.0001834483],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0108894,"threshold_uncertainty_score":0.999526,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005759629265320945,"score_gpt":0.1914423569095212,"score_spread":0.1856827276442002,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}